182196-14-1Relevant academic research and scientific papers
o-Hydroxyarylphosphines and diphosphines: Metallation-rearrangement versus P-O reduction of o-halogenoaryloxyphosphines by sodium
Heinicke, Joachim,Kadyrov, Renat
, p. 131 - 137 (2007/10/03)
o-Bromo-and o-chloroaryloxyphosphines 1 may react with sodium in two competing ways: (i) metal halogen exchange followed by rapid intramolecular 1,3-rearrangement to give sodium o-hydroxylato-arylphosphines 2, later converted to their OSiMe3 de
P/O ligand systems: Synthesis, reactivity, structure of tertiary o-phosphanylphenol derivatives
Heinicke, Joachim,Kadyrov, Renat,Kindermann, Markus K.,Koesling, Manuela,Jones, Peter G.
, p. 1547 - 1560 (2007/10/03)
Reactions of C,O-dilithium reagents 1 (M = M′ = Li) or C,O-lithium-sodium reagents 1 (M = Li, M′ = Na) with chlorophosphanes afford C,O-disubstitution products 2 or phosphanylphenolates 3 which are treated subsequently with ClSiMe3 to give 4-me
