182233-50-7Relevant academic research and scientific papers
Structural studies on indium and tin thiobenzoates
Singh,Bhattacharya,Gupta, Vishnu D.,Noeth, Heinrich
, p. 1093 - 1098 (1996)
Indium(III) and tin(IV) thiocarboxylates were prepared and characterized on the basis of their IR, 13C- and 19Sn-NMR data. Indium tris(thiobenzoate) (1) decomposes into a sulfido complex In(S)(S(O)CPh] (2a). The corresponding tris(thioacetate) In[S(O)CMe]3 is thermally too unstable to be isolated. The anionic tetrakis complex [Et3NH]iIn[S(O)CPh]4) (3) was characterized by X-ray crystallography which revealed a distorted tetrahedral coordination at the In atom. X-ray diffraction analysis of the complexes BuSn[S(O)CPh]3 (4) and Cl2Sn[S(O)CPh]2 (7) showed distorted tetrahedral and tis-octahedral structures, respectively. VCH Veriagsgesellschaft mbH, 1996.
