182243-64-7

Basic information

• Product Name: Methanesulfonic acid (1S,2R)-3-(tert-butyl-diphenyl-silanyloxy)-1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2-methyl-propyl ester
• Synonyms: Methanesulfonic acid (1S,2R)-3-(tert-butyl-diphenyl-silanyloxy)-1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2-methyl-propyl ester
• CAS NO: 182243-64-7
• Molecular Weight: 689.076
• Mol File: 182243-64-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methanesulfonic acid (1S,2R)-3-(tert-butyl-diphenyl-silanyloxy)-1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2-methyl-propyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Methanesulfonic acid (1S,2R)-3-(tert-butyl-diphenyl-silanyloxy)-1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2-methyl-propyl ester(182243-64-7)
• EPA Substance Registry System: Methanesulfonic acid (1S,2R)-3-(tert-butyl-diphenyl-silanyloxy)-1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2-methyl-propyl ester(182243-64-7)

Safety Data

• Hazardous Substances Data: 182243-64-7(Hazardous Substances Data)

Upstream product

• 124-63-0 methanesulfonyl chloride 
• 182243-55-6 (2R,3S)-1,5-Bis-(tert-butyl-diphenyl-silanyloxy)-2-methyl-pentan-3-ol 

Downstream Products

• 182243-78-3 Acetic acid (1R,2R)-3-(tert-butyl-diphenyl-silanyloxy)-1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2-methyl-propyl ester 
• 182243-65-8 Chloro-methanesulfonic acid (1S,2R)-3-(tert-butyl-diphenyl-silanyloxy)-1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2-methyl-propyl ester 

Relevant articles and documents

Efficient method for inversion of secondary alcohols by reaction of chloromethanesulfonates with cesium acetate

Inversion of a variety of secondary alcohols using the (chloromethylsulfonyl)oxy group as a favorable leaving group with cesium acetate in the presence of 18-crown-6 has been performed to give the inverted acetates in high yields.