18265-35-5

Upstream product

• 108-24-7 acetic anhydride 
• 123-31-9 hydroquinone 
• 1415680-12-4 2-(2,3,4,6-tetra-О-acetyl-β-D-glucopyranozyloxy)-5-acetyloxybenzyl alcohol 
• 98-88-4 benzoyl chloride 
• 64418-88-8 2-hydroxy-5-acetyloxybenzaldehyde 
• 1415680-10-2 2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy)-5-acetyloxybenzaldehyde 
• 3233-32-7 hydroquinone monoacetate 

Downstream Products

• 16955-55-8 2-benzoyloxymethyl-4-hydroxyphenyl β-D-glucopyranoside 

Relevant academic research and scientific papers

First total chemical synthesis of natural acyl derivatives of some phenolglycosides of the family Salicaceae

The total synthesis of certain natural phenolglycosides of the family Salicaceae, namely: salireposide, populosides A, B, and C and not occurring in plants desoxysalireposide (2-(β-d-glucopyranosyloxy)-benzylbenzoate) and per-acetate of iso-salireposide (2-(β-d-glucopyranosyloxy)-5-benzoyloxy benzyl alcohol), starting from readily available phenols and glucose was accomplished. A simple method for the synthesis of phenolglycosides derivatives of 2-acyloxy salicyl and gentisyl alcohol was developed. The key step of these natural products' synthesis is a selective removal of acetyl groups in the presence of other acyl groups.