18266-47-2

Basic information

• Product Name: methyl phenanthrene-4-carboxylate
• Synonyms: Methyl 4-phenanthrenecarboxylate
• CAS NO: 18266-47-2
• Molecular Formula: C₁₆H₁₂O₂
• Molecular Weight: 236.2653
• Mol File: 18266-47-2.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 405.4°C at 760 mmHg
• Flash Point: 194.3°C
• Density: 1.208g/cm³
• Vapor Pressure: 8.81E-07mmHg at 25°C
• Refractive Index: 1.677
• CAS DataBase Reference: methyl phenanthrene-4-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl phenanthrene-4-carboxylate(18266-47-2)
• EPA Substance Registry System: methyl phenanthrene-4-carboxylate(18266-47-2)

Safety Data

• Hazardous Substances Data: 18266-47-2(Hazardous Substances Data)

Upstream product

• 866528-96-3 3-((E)-Propenyl)-2-trifluoromethanesulfonyloxy-benzoic acid methyl ester 
• 15016-42-9 2-vinylbenzeneboronic acid 
• 119-36-8 methyl salicylate 
• 31456-98-1 methyl 3-allyl-salicylate 
• 101110-12-7 1,2-dihydro-phenanthrene-4-carboxylic acid methyl ester 

Downstream Products

• 22863-79-2 4‐phenanthrenemethanol 
• 26698-30-6 2-(Phenanthrene-4-carbonyl)-malonic acid diethyl ester 
• 26687-67-2 9,10-Dibromo-9,10-dihydro-phenanthrene-4-carboxylic acid 
• 26698-23-7 10-Bromo-phenanthrene-4-carboxylic acid methyl ester 
• 26698-24-8 10-Chloro-phenanthrene-4-carboxylic acid methyl ester 
• 17423-48-2 4-phenanthrenamine 
• 5737-13-3 cyclopenta[def]phenanthren-4-one 
• 26847-76-7 9,10-Dibromo-9,10-dihydro-phenanthrene-4-carboxylic acid methyl ester 

Relevant articles and documents

Studies towards the total synthesis of Sch 56036; isoquinolinone synthesis and the synthesis of phenanthrenes

The isoquinolinone hemisphere of Sch 56036 has been prepared using a modified Pomeranz-Fritsch reaction and the synthesis of the phenanthrene core has been modelled via a Suzuki coupling and subsequent ring closing metathesis.