182694-58-2Relevant academic research and scientific papers
Reactions of N-sulfinylfluoroalkanesulfonylamides with alkene oxides
Zhu, Shizheng,Zhang, Jie,Xu, Bin,Jin, Xianglin
, p. 49 - 52 (1996)
Reactions of N-sulfinylfluoroalkanesulfonylamides, RfSO2NSO (1), with alkene oxides 2 at room temperature gave the cyclo condensation products 2-oxa-3-fluoroalkanesulfonyl-1,2,3-oxathiazolidines, RfSO2NCH(R)CH2OS(O) (3). When R was phenyl, the compound decomposed at 160 °C to give N-fluoroalkanesulfonylaziridine, R1SO2NCH2CH(C6H5), with elimination of SO2. Acidic hydrolysis of 3c [Rf=I(CF2) 2O(CF2)2, R=Ph] gave RfSO2NHCH(Ph)CH2OH (5) which was identified by X-ray diffraction analysis.
