183023-15-6

Basic information

• Product Name: 2H-1,4-Oxazin-2-one, 5,6-dihydro-5-phenyl-, (5S)-
• CAS NO: 183023-15-6
• Molecular Formula: C10H9NO2
• Molecular Weight: 175.187
• Mol File: 183023-15-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2H-1,4-Oxazin-2-one, 5,6-dihydro-5-phenyl-, (5S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-1,4-Oxazin-2-one, 5,6-dihydro-5-phenyl-, (5S)-(183023-15-6)
• EPA Substance Registry System: 2H-1,4-Oxazin-2-one, 5,6-dihydro-5-phenyl-, (5S)-(183023-15-6)

Safety Data

• Hazardous Substances Data: 183023-15-6(Hazardous Substances Data)

Upstream product

• 144896-92-4 (5S)-5-phenylmorpholin-2-one 
• 20989-17-7 (2S)-2-phenylglycinol 
• 222622-39-1 (4S)-4,5-dihydro-2-methyl-4-phenyl-1,3-oxazole 

Downstream Products

• 1214274-52-8 (3S,5S)-3-allyl-5-phenylmorpholin-2-one 
• 881099-31-6 (3S,5S)-3-(2-methylallyl)-5-phenyl-3,4,5,6-tetrahydro-1,4-oxazin-2-one 
• 1214274-57-3 (3R,5S)-3-(2-methylallyl)-5-phenyl-3,4,5,6-tetrahydro-1,4-oxazin-2-one 
• 1214274-54-0 (3S,5S)-3-(2-methylbut-3-en-2-yl)-5-phenylmorpholin-2-one 
• 1355544-39-6 methyl 2-((3S,5S)-4-acetyl-2-oxo-5-phenylmorpholine-3-carboxamido)acetate 
• 1355544-44-3 methyl 2-((3S,5S)-4-formyl-2-oxo-5-phenylmorpholine-3-carboxamido)acetate 
• 1355544-42-1 (3S,5S)-N-benzyl-4-formyl-2-oxo-5-phenylmorpholine-3-carboxamide 
• 1355545-35-5 (3S,5S)-N-tert-butyl-4-formyl-2-oxo-5-phenylmorpholine-3-carboxamide 

Relevant articles and documents

Synthesis, isomerisation and Diels-Alder reactions of (5S)-5-phenyl-3,4-dehydromorpholin-2-one

(5S)-5-Phenyl-3,4-dehydromorpholin-2-one [(5S)-5-phenyl-5,6-dihydro-2H-1,4-oxazin-2-one] 2a is prepared by a one-pot bromination/dehydrobromination of (5S)-5-phenyl morpholin-2-one and undergoes regio- and diastereocontrolled catalysed Diels-Alder reactio

Diastereoselective allylstannane additions to (S)-5,6-dihydro-2H-5- phenyloxazin-2-one. A concise synthesis of (S)-β-methylisoleucine

Chemical Equation Presented The addition of allyl stannanes to (S)-4,5-dihydro-5-phenyl-2H-oxazinone (3) was achieved under Bronsted acid catalysis to give 2-allylmorpholinones with high diastereoselectivity (up to dr 14.2:1). The product of dimethylallyltributylstannane addition to 3 was converted to L-β-methylisoleucine, an α-amino acid residue found In the complex, biologically active marine-derived peptides polytheonamides A and B, and polydiscamides A-C.