18317-65-2Relevant academic research and scientific papers
On the Mechanism of the Thermal Decomposition of 1-Bromo-1-(trimethylstannyl)cyclopropanes
Warner, Philip M.,Herold, Robert D.,Chu, I-Shan,Lessman, Jeffrey
, p. 942 - 950 (1988)
A mechanistic study of the thermolysis of compounds 4a and 4b is reported.In methanolic benzene, 4a reacts entirely via formation of norcaranylidene (8), while 4b gives no carbene but rather ring-opening to a cycloheptenyl ion.The pathway for carbene form
Silyl Tosylate Precursors to Cyclohexyne, 1,2-Cyclohexadiene, and 1,2-Cycloheptadiene
McVeigh, Matthew S.,Kelleghan, Andrew V.,Yamano, Michael M.,Knapp, Rachel R.,Garg, Neil K.
supporting information, p. 4500 - 4504 (2020/06/08)
Transient strained cyclic intermediates have become valuable intermediates in modern synthetic chemistry. Although silyl triflate precursors to strained intermediates are most often employed, the instability of some silyl triflates warrants the developmen
