Journal of Organic Chemistry p. 942 - 950 (1988)
Update date:2022-08-29
Topics:
Warner, Philip M.
Herold, Robert D.
Chu, I-Shan
Lessman, Jeffrey
A mechanistic study of the thermolysis of compounds 4a and 4b is reported.In methanolic benzene, 4a reacts entirely via formation of norcaranylidene (8), while 4b gives no carbene but rather ring-opening to a cycloheptenyl ion.The pathway for carbene form
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