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Silane, [(2-bromophenyl)methyl]trimethyl-, also known as (2-bromophenyl)methyltrimethylsilane or 2-bromobenzyltrimethylsilane, is an organosilicon compound with the chemical formula C10H15BrSi. It is a colorless liquid at room temperature and is soluble in organic solvents. Silane, [(2-bromophenyl)methyl]trimethyl- is primarily used as a reagent in organic synthesis, particularly in the formation of carbon-carbon bonds through the Stille coupling reaction, a type of cross-coupling reaction. It is also employed as a protecting group in the synthesis of various organic compounds due to its stability and ease of removal. The compound is sensitive to moisture and air, and should be stored under an inert atmosphere to prevent degradation.

1833-44-9

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1833-44-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1833-44-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,8,3 and 3 respectively; the second part has 2 digits, 4 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 1833-44:
(6*1)+(5*8)+(4*3)+(3*3)+(2*4)+(1*4)=79
79 % 10 = 9
So 1833-44-9 is a valid CAS Registry Number.

1833-44-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-bromo-2-((trimethylsilyl)methyl)benzene

1.2 Other means of identification

Product number -
Other names o-Brom-benzyltrimethylsilan

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1833-44-9 SDS

1833-44-9Relevant academic research and scientific papers

Benzylic Grignard Reagents: Application of (thf = tetrahydrofuran) in Regioselective Grignard Formation and C-O Cleavage in Benzyl Ethers

Gallagher, Michael J.,Harvey, Stephen,Raston, Colin L.,Sue, Rodney E.

, p. 289 - 290 (2007/10/02)

Benzylic Grignard reagents (2)-(4), bearing ortho- and para-halogeno ring substituents, are readily accessible by treating the corresponding benzylic halide with (1) in tetrahydrofuran (thf); o- and p-chloromethyl(methoxymethyl)benzenes with (1) rapidly yield 'di-Grignards' whereas the meta-isomer only affords a mono-Grignard' (5), and bis(methoxymethyl)benzenes slowly undergo C-O cleavage, (6).

Substitution electrophile originale (en position benzylique), avec le benzyltrimethylsilane

Bordeau, Michel,Villeneuve, Patrice,Bennetau, Bernard,Dunogues, Jacques

, p. 169 - 174 (2007/10/02)

Benzyltrimethylsilane reacts with iodine monobromide, bromine in the presence of iodine as catalyst, or bromine under electrophilic substitution either on the aromatic ring or at the benzylic position.The for the first time observed direct benzylic substi

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