183323-89-9

Upstream product

• 7244-78-2 1-butoxy-4-nitrobenzene 
• 13257-51-7 mercury(II) trifluoroacetate 

Downstream Products

• 183323-92-4 N(CH₃)4⁽¹⁺⁾*AuCl₃(O₂NC₆H₃OC₄H₉)^(1-) = [N(CH₃)4][AuCl₃(O₂NC₆H₃OC₄H₉)] 
• 183323-93-5 [AuCl₂(P(C₆H₅)3)(O₂NC₆H₃OC₄H₉)] 
• 183323-94-6 [AuCl(C₆H₃(NO₂)OC₄H₉)(C₆H₄NNC₆H₅)] 
• 183323-90-2 Hg(C₆H₃(NO₂)OC₄H₉)2 

Relevant academic research and scientific papers

Synthesis and reactivity of some nitroaryl complex of HgII and AuIII synthesis of a substituted biphenyl by C-C coupling - Crystal structure of [Hg(C6H4NO2-3,OnBu-6)2]

4-Butoxynitrobenzene reacts with [Hg(O2CCF3)2] and LiCl to give [Hg(R)Cl] [R = C6H3NO2-3,OnBu-6 (1)] which is symmetrized by Me4NCl to give [HgR2] (2), the crystal structure of which has been determined. The reaction of 2 with Me4N[AuCl4] affords Me4NlAu(R)Cl3] (3) by a facile transmetallation process. Complex 3 reacts with PPh3 (1:1) to give cis-[Au(R)(PPh3)Cl2] (4). The diaryl complex [Au(C6H4N=N-Ph-2)(R)Cl] (5) is obtained by reaction of 3 with [Hg-(C6H4N=NPh-2)2] through a second transmelallation reaction. Complex 5 and PPh3 (1:1) give [AuClPPh3] and the C-C coupling biphenyl RC6iH4N=NPh-2 (6). VCH Verlagsgesellschaft mbH, 1996.