18335-31-4Relevant academic research and scientific papers
Rearrangement of cyclopropylborane into boretane
Rubina, M.,Rubin, M.
, p. 807 - 821,15 (2012)
Previously unknown boron-containing four-membered unsaturated heterocycle boretane was obtained via novel thermal rearrangement of cyclopropylborane and investigated by NMR and IR spectroscopy. Formation of boretane was also confirmed through its chemical
TETRAISOPROPOXYTITANIUM-CATALYZED REACTION OF ALKYLMAGNESIUM HALIDES WITH ESTERS AS A CONVENIENT METHOD FOR THE PRODUCTION OF SUBSTITUTED CYCLOPROPANOLS
Kulinkovich, O. G.,Vasilevskii, D. A.,Savchenko, A. I.,Sviridov, S. V.
, p. 1249 - 1251 (2007/10/02)
The reaction of alkylmagnesium halides with carboxylic esters at room temperature in the presence of tetraisopropoxytitanium gives good yields of the respective 1-substituted cyclopropanols.
REACTION OF ALKYLMAGNESIUM HALIDES WITH CARBOXYLIC ESTERS IN THE PRESENCE OF TETRAISOPROPOXYTITANIUM
Kulinkovich, O.G.,Sviridov, S.V.,Vasilevskii, D.A.,Savchenko, A.I.,Pritytskaya, T.S.
, p. 250 - 253 (2007/10/02)
The reaction of carboxylic esters with a threefold molar excess of ethylmagnesium bromide in the presence of an equimolar amount of tetraisopropoxytitanium leads to the formation of the corresponding 1-substituted 1-cyclopropanols.Propyl-, butyl-,and 2-phenylethylmagnesium bromides enter into a similar reaction, leading to 1,2-disubstituted 1-cyclopropanols.
