18365-70-3

Basic information

• Product Name: ALLYL N-HEXYL SULPHIDE
• Synonyms: ALLYL N-HEXYL SULPHIDE;Allyln-hexylsulfide
• CAS NO: 18365-70-3
• Molecular Formula: C₉H₁₈S
• Molecular Weight: 158.3
• Mol File: 18365-70-3.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 208.6°C at 760 mmHg
• Flash Point: 68.9°C
• Appearance: /
• Density: 0.85g/cm³
• Vapor Pressure: 0.305mmHg at 25°C
• Refractive Index: 1.465
• CAS DataBase Reference: ALLYL N-HEXYL SULPHIDE(CAS DataBase Reference)
• NIST Chemistry Reference: ALLYL N-HEXYL SULPHIDE(18365-70-3)
• EPA Substance Registry System: ALLYL N-HEXYL SULPHIDE(18365-70-3)

Safety Data

• Statements: R36/38:Irritating to eyes and skin.
• Safety Statements: S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.; S36:Wear suitable prot
• Hazardous Substances Data: 18365-70-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H18S/c1-3-5-6-7-9-10-8-4-2/h4H,2-3,5-9H2,1H3

Upstream product

• 111-31-9 Hexanethiol 
• 106-95-6 allyl bromide 
• 10496-15-8 dihexyl disulfide 
• 346713-20-0 allylsamarium bromide 
• 591-87-7 Allyl acetate 
• 107-18-6 allyl alcohol 
• 175603-23-3 1-[((E)-But-2-enyl)sulfanyl]-hexane 
• 18888-20-5 n-hexyl-vinyl sulfide 
• 41051-08-5 C₆H₁₃O₃S₂^(1-)*Na⁽¹⁺⁾ 

Downstream Products

• 111-31-9 Hexanethiol 
• 24768-43-2 hexyl-propyl sulfide 

Relevant articles and documents

A novel synthesis of allyl sulfides in aqueous media promoted by indium

Allyl bromides react smoothly with sodium alkyl thiosulfates promoted by indium in aqueous media to give allyl sulfides in moderate to good yields.

Scope of the allylation reaction with [RuCp(PP)]+ catalysts: Changing the nucleophile or allylic alcohol

The scope of the dehydrative allylation reaction using allyl alcohol as allyl donor with [RuCp(PP)]+ complexes as catalysts is explored. Aliphatic alcohols are successfully allylated with allyl alcohol or diallyl ether, obtaining high selectivity for the alkyl allyl ether. The reactivity of aliphatic alcohols is in the order of primary > secondary tertiary. The tertiary alcohol 1-adamantanol reacts extremely slowly in the absence of strong acid, but when HOTs is added, reasonable yields of 1-adamantyl allyl ether are obtained. The alkyl allyl ether is found to be the thermodynamically favored product over diallyl ether. Apart from alcohols, thiols and indole are also efficiently allylated, while aniline acts as a catalyst inhibitor. Allylation reactions with various substituted allylic alcohols give products with retention of the substitution pattern. It is proposed that a Ru(IV) σ-allyl species plays a key role in the mechanism of these allylation reactions.

Process for producing allyl-containing compounds

An allyl-containing compound represented by following Formula (3): wherein R2, R3, R4, R5 and R6 may be the same as or different from one another and each represent hydrogen atom or an organic group; R7 represents an organic group; and Y represents oxygen atom or sulfur atom, is produced by reacting an allyl ester compound represented by following Formula (1): wherein R1 represents hydrogen atom or an organic group; and R2, R3, R4, R5 and R6 are as defined above, with a compound represented by following Formula (2):R7-Y-H wherein R7 is an organic group; and Y is as defined above, in the presence of at least one transition element compound.