183891-62-5Relevant academic research and scientific papers
Synthesis and photophysics of dinuclear gold(I) thiolates of bis(diphenylphosphino)-alkyl- and -aryl-amines. Crystal structure of [Au2{Ph2PN(C6H11)PPh 2}(SC6H4F-p)2]
Yam, Vivian Wing-Wah,Chan, Chui-Ling,Cheung, Kung-Kai
, p. 4019 - 4022 (1996)
A series of luminescent dinuclear gold(I) thiolates, [Au2{Ph2PN(R)PPh2}(SR′)2] (R = C6H11, R′ = C6H4F-p, C6H4Cl-p, C6H4Me-p; R = Ph, R′ = C6H4Me-p; R = Prn, R′ = C6H4Me-p; R = Pri, R′ = C6H4Me-p) have been synthesized and their photophysical properties studied. The crystal structure of [Au2{Ph2PN(C6H11)PPh 2}(SC6H4F-p)2] has been determined. These complexes have been shown to exhibit low-energy emission at ca. 600 nm, attributed to a ligand-to-metal charge transfer (thiolate to AuI) origin.
