Synthesis and photophysics of dinuclear gold(I) thiolates of bis(diphenylphosphino)-alkyl- and -aryl-amines. Crystal structure of [Au2{Ph2PN(C6H11)PPh 2}(SC6H4F-p)2]

DOI: 10.1039/dt9960004019

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 4019 - 4022 (1996)

Update date:2022-08-03

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Authors:

Yam, Vivian Wing-Wah

Chan, Chui-Ling

Cheung, Kung-Kai

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Article abstract of DOI:10.1039/dt9960004019

A series of luminescent dinuclear gold(I) thiolates, [Au₂{Ph₂PN(R)PPh₂}(SR′)₂] (R = C₆H₁₁, R′ = C₆H₄F-p, C₆H₄Cl-p, C₆H₄Me-p; R = Ph, R′ = C₆H₄Me-p; R = Prⁿ, R′ = C₆H₄Me-p; R = Prⁱ, R′ = C₆H₄Me-p) have been synthesized and their photophysical properties studied. The crystal structure of [Au₂{Ph₂PN(C₆H₁₁)PPh ₂}(SC₆H₄F-p)₂] has been determined. These complexes have been shown to exhibit low-energy emission at ca. 600 nm, attributed to a ligand-to-metal charge transfer (thiolate to Au^I) origin.

Full text of DOI:10.1039/dt9960004019

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