18395-82-9Relevant articles and documents
Formation of a new crystalline silicate structure by grafting dialkoxysilyl groups on layered octosilicate
Mochizuki, Dai,Shimojima, Atsushi,Kuroda, Kazuyuki
, p. 12082 - 12083 (2002)
Dialkoxydichlorosilanes ((RO)2SiCl2, R = alkyl) react almost completely with interlayer silanol groups in a layered silicate octosilicate to create a new crystalline silicate structure consisting of new five-membered rings arranged regularly on both sides of the silicate layers. The introduction of dialkoxysilyl groups to the interlamellar region of layered silicates with regular reaction sites provides a new methodology for the design and construction of novel crystalline silicate frameworks by a soft chemical route. Copyright
Versatile method for introduction of bulky substituents to alkoxychlorosilanes
Masaoka, Shin,Banno, Tadashi,Ishikawa, Mitsuo
, p. 182 - 192 (2007/10/03)
The reactions of various alkoxytrichlorosilanes prepared in situ from tetrachlorosilane and alcohols, with Grignard reagents bearing a bulky substituent such as the isopropyl, sec-butyl, and cyclohexyl group afforded triisopropyl-, tri(sec-butyl)-, and tricyclohexylalkoxysilane in high yields. The reactions of n-butoxytrichlorosilane with these Grignard reagents produced triisopropyl-, tri(sec-butyl)-, and tricyclohexyl(n-butoxy)silane in 94%, 96%, and 92% yields, respectively. Methoxymethyldichlorosilane reacted with the same Grignard reagents to give diisopropyl-, di(sec-butyl)-, and dicyclohexylmethoxymethylsilane in 84%, 83%, and 83% yields. Treatment of methoxydimethylchlorosilane with the Grignard reagents readily afforded isopropyl-, sec-butyl-, and cyclohexylmethoxydimethylsilane in excellent yields. Similar treatment of methoxydimethylchlorosilane with tert-butylmagnesium chloride gave tert-butylmethoxydimethylsilane in 62% yield.
Studies on Silicon-Nitrogen Compounds: Part V - Preparation and Characterisation of Some Substituted Organoaminoalkoxysilanes
Narula, Suraj P.,Kapur, Neeta,Shankar, Ravi,Mittal, Satish,Chodha, Arun,Kumar, Suniti
, p. 112 - 114 (2007/10/02)
Benzylamino/n-butylamino/2-chloroanilino/2,4-difluoroanilino/2-fluoroanilino/4-methylanilino-bis(2,2,2-trifluoroethoxy)methyl/bis(2,2,2-trifluoroethoxy)n-propoxy/tris(2,2,2-trifluoro-ethoxy)/tri-n-propoxy-silanes as well as bis(2-chloroanilino)/(2-fluoroa