183955-08-0Relevant academic research and scientific papers
Diastereoselective synthesis of trifluoromethylated 1,3-dioxanes by intramolecular oxa-Michael reaction
Becerra-Figueroa, Liliana,Brun, Elodie,Mathieson, Michael,Farrugia, Louis J.,Wilson, Claire,Prunet, Jo?lle,Gamba-Sánchez, Diego
supporting information, p. 301 - 305 (2017/01/13)
A highly diastereoselective synthesis of trifluoromethylated 1,3-dioxanes is described. The reaction proceeds by an addition/oxa-Michael sequence and works efficiently under mild reaction conditions, with a good substrate scope and acceptable to good yiel
A New, Simple, and Selective Palladium-Catalyzed Cleavage of Triethylsilyl Ethers
Rotulo-Sims, Delphine,Prunet, Joelle
, p. 4701 - 4704 (2007/10/03)
(Equation Presented) A simple procedure for the cleavage of triethylsilyl (TES) ethers in the presence of 10 wt % Pd/C in methanol or 95% ethanol is reported. This method allows selective removal of alkyl TES ethers in the presence of aromatic TES ethers or tert-butyldimethylsilyl (TBS) protecting groups.
