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Cycloheptanone ethane-1,2-diyl dithioacetal is a chemical compound with the molecular formula C9H16OS2. It is a cyclic ketone derivative, where the carbonyl group (C=O) is part of a seven-membered ring (cycloheptanone). The ethane-1,2-diyl dithioacetal functional group is attached to the carbonyl carbon, which involves two sulfur atoms bonded to the carbon atoms of ethylene (C2H4), forming a dithioacetal structure. Cycloheptanone ethane-1,2-diyl dithioacetal is known for its unique chemical properties and is used in various organic synthesis processes, particularly in the formation of complex molecules and as a protecting group in organic chemistry. It is also recognized for its potential applications in the pharmaceutical and chemical industries due to its ability to stabilize certain functional groups during reactions.

184-32-7

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184-32-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 184-32-7 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,8 and 4 respectively; the second part has 2 digits, 3 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 184-32:
(5*1)+(4*8)+(3*4)+(2*3)+(1*2)=57
57 % 10 = 7
So 184-32-7 is a valid CAS Registry Number.
InChI:InChI=1/C9H16S2/c1-2-4-6-9(5-3-1)10-7-8-11-9/h1-8H2

184-32-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,4-Dithiaspiro(4.6)undecane

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:184-32-7 SDS

184-32-7Downstream Products

184-32-7Relevant academic research and scientific papers

Silica-supported phosphorus pentoxide: A reusable catalyst for S,S-acetalization of carbonyl groups under ambient conditions

Shaterian, Hamid Reza,Azizi, Kobra,Fahimi, Nafiseh

experimental part, p. 85 - 91 (2012/01/06)

Phosphorus pentoxide supported on silica gel (P2O 5/SiO2) efficiently acts as a highly active and reusable catalyst for cyclic and non-cyclic S,S-acetalization of a variety of carbonyl compounds under mild, solvent-free an

Efficient method for thioacetalization of carbonyl compounds in the presence of a catalytic amount of benzyltriphenylphosphonium tribromide (BTPTB) under solvent-free conditions

Hajipour, Abdol Reza,Pourmousavi, Seied A.,Ruoho, Arnold E.

, p. 2548 - 2566 (2008/12/22)

A variety of carbonyl compounds have been successfully converted to the corresponding thioacetal derivatives in good to excellent yields on reaction of carbonyl compounds with 1,2-ethanedithiole, 1,3-propanedithiol, and ethylthiol in the presence of a cat

An efficient method for thioacetalization of carbonyl compounds in the presence of a catalytic amount of benzyltriphenylphosphonium tribromide under solvent-free conditions

Hajipour, Abdol R.,Pourmousavi, Seied A.,Ruoho, Arnold E.

, p. 921 - 937 (2008/02/05)

A variety of carbonyl compounds have been successfully converted to the corresponding thioacetal derivatives in good to excellent yields on the reaction of carbonyl compounds with 1,2-ethanedithiole, 1,3-propanedithiol, and ethanethiol in the presence of

Perchloric acid adsorbed on silica gel (HClO4-SiO2) as an extremely efficient and reusable catalyst for 1,3-dithiolane/dithiane formation

Rudrawar, Santosh,Besra, Ram C.,Chakraborti, Asit K.

, p. 2767 - 2771 (2008/02/05)

Perchloric acid adsorbed on silica gel (HClO4-SiO2) has been found to be an extremely efficient and reusable catalyst for 1,3-dithiolane and 1,3-dithiane formation under solvent-free conditions at room temperature. Georg Thieme Verla

A mild and chemoselective catalyst for thioacetalization under solvent free conditions

Hajipour, Abdol R.,Zarei, Amin,Khazdooz, Leila,Zahmatkesh, Saeed,Ruoho, Arnold E.

, p. 387 - 395 (2007/10/03)

Protection of a variety of carbonyl compounds as dithioacetals using P 2O5/SiO2 (75%), as a mild and chemoselective catalyst, was achieved under solvent free conditions in very good yields. Copyright Taylor & Francis Group

Copper(II) tetrafluoroborate as an extremely efficient catalyst for 1,3-dithiolane/dithiane formation from carbonyl compounds under solvent-free conditions at room temperature

Besra, Ram C.,Rudrawar, Santosh,Chakraborti, Asit K.

, p. 6213 - 6217 (2007/10/03)

Copper(II) tetrafluoroborate hydrate is a new and extremely efficient catalyst for 1,3-dithiolane/dithiane formation from aromatic, heteroaromatic and aliphatic aldehydes and cyclic saturated ketones in 1-5 min under solvent-free conditions at room temper

A simple and efficient heterogeneous procedure for thioacetalization of aldehydes and ketones

Ali, Mohammed Hashmat,Gomes, Maria Goretti

, p. 1326 - 1332 (2007/10/03)

A new procedure for the protection of aldehydes and ketones as thioacetals promoted by catalytic amount of p-toluene-sulfonic acid and silica gel has been developed. This procedure offers versatility, short reaction time, excellent yield, good selectivity

A simple and practical synthetic protocol for acetalisation, thioacetalisation and transthioacetalisation of carbonyl compounds under solvent-free conditions

Khan, Abu T.,Mondal, Ejabul,Ghosh, Subrata,Islam, Samimul

, p. 2002 - 2009 (2007/10/03)

A wide variety of carbonyl compounds can be converted smoothly to the corresponding acetals on treatment with alcohols or diols and triethyl orthoformate in the presence of a catalytic amount of (bromodimethyl)sulfonium bromide at room temperature. Similarly, various carbonyl compounds can be transformed into the corresponding dithioacetals on reaction with thiol or dithiols at room temperature by employing the same catalyst without any solvent. Moreover, O,O-acetals can also be converted into the corresponding dithioacetals under identical conditions. Some of the major advantages are mild reaction conditions, a high degree of efficiency, compatibilty with other protecting groups and the lack of solvents, particularly for thioacetalisation. In addition, no brominations occur at the double bond or α to the keto position or even in the aromatic ring under these experimental conditions. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

Indium triflate: A mild Lewis acid catalyst for thioacetalization and transthioacetalization

Muthusamy, Sengodagounder,Arulananda Babu, Srinivasarao,Gunanathan, Chidambaram

, p. 7897 - 7901 (2007/10/03)

Protection of a variety of carbonyl compounds as thioacetals using indium triflate, a mild Lewis acid catalyst, was achieved at ambient temperature in very good yield. Transthioacetalization of oxyacetals into thioacetals was also achieved in an excellent

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