18408-00-9Relevant academic research and scientific papers
Platinum complexes bearing a boron-based PBP pincer ligand: Synthesis, structure, and application as a catalyst for hydrosilylation of 1-decene
Ogawa, Hayato,Yamashita, Makoto
, p. 625 - 629 (2013)
Four platinum(ii) complexes bearing a boron-based PBP pincer ligand and chloride, hydride, triflate, and bis(trifluoromethanesulfonyl)imide were synthesized and structurally characterized. PBP-platinum chloride was proven to be an active catalyst for the hydrosilylation reaction using 1-decene and triethylsilane.
METHOD FOR PRODUCING ORGANOSILICON COMPOUND BY HYDROSILYLATION WITH METALLIC-ELEMENT-CONTAINING NANOPARTICLES
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Paragraph 0091-0093; 0096, (2019/11/21)
An organosilicon compound can be efficiently produced by using metallic element-containing nanoparticles such as a platinum element-containing nanoparticle having a solvent on surface as a catalyst of the hydrosilylation reaction of alkenes.
Metal-Organic Frameworks Stabilize Mono(phosphine)-Metal Complexes for Broad-Scope Catalytic Reactions
Sawano, Takahiro,Lin, Zekai,Boures, Dean,An, Bing,Wang, Cheng,Lin, Wenbin
supporting information, p. 9783 - 9786 (2016/08/19)
Mono(phosphine)-M (M-PR3; M = Rh and Ir) complexes selectively prepared by postsynthetic metalation of a porous triarylphosphine-based metal-organic framework (MOF) exhibited excellent activity in the hydrosilylation of ketones and alkenes, the hydrogenation of alkenes, and the C-H borylation of arenes. The recyclable and reusable MOF catalysts significantly outperformed their homogeneous counterparts, presumably via stabilizing M-PR3 intermediates by preventing deleterious disproportionation reactions/ligand exchanges in the catalytic cycles.
Desulfurizative silation, germation, and stannation of thioacetals and their analogues utilizing titanocene(II)
Takeda, Takeshi,Nozaki, Naoki,Fujiwara, Tooru
, p. 3533 - 3536 (2007/10/03)
Desulfurization of thioacetals with the low valent titanium species CP2Ti[P(OEt)3]2 in the presence of trialkylsilanes afforded the corresponding tetraalkylsilanes. Allylsilanes were obtained regioselectively using β,γ-uns
