184154-64-1Relevant academic research and scientific papers
Para -Selective copper-catalyzed C(sp2)-H amidation/dimerization of anilides via a radical pathway
Viveki, Amol B.,Garad, Dnyaneshwar N.,Gonnade, Rajesh G.,Mhaske, Santosh B.
supporting information, p. 1565 - 1568 (2020/02/13)
Copper-catalyzed amidation/dimerization of anilides via regioselective C(sp2)-H functionalization is achieved. The para-selective amidation is accomplished on the anilide aromatic ring via a radical pathway leading to C-N bond formation in the presence of ammonium persulfate as a radical source/oxidant for the copper catalyst. The developed protocol tolerates a wide range of anilide substrates. The regioselectivity is confirmed by single-crystal X-ray studies.
Design, synthesis and characterization of novel nitrogen- and sulfur-containing polymers with well-defined conjugated length
Zhu, Kaizheng,Wang, Lixiang,Jing, Xiabin,Wang, Fosong
, p. 181 - 187 (2007/10/03)
A series of novel nitrogen- and sulfur-containing conjugated polymers with well-defined conjugation length have been synthesized via an acid-induced self-polycondensation of functional monomers with methylsulfinyl groups. Synthesized polymers exhibit good
Stable triplet-state di(cation radicals) of a meta-para aniline oligomer by 'acid doping'
Wienk, Martijn M.,Janssen, René A. J.
, p. 10626 - 10628 (2007/10/03)
We describe the formation of a stable triplet-state oligoaniline di(cation radical) via a proton-triggered redox reaction between N,N'-bis[4-(phenylamino)phenyl]-1,3-benzenediamine (1) and N,N'-bis[4-(phenylimino)cyclohexa-2,5-dienylidene]-1,3-benzenediam
