184178-86-7

Basic information

• Product Name: 1-Oxaspiro[2.5]octane,7-methyl-4-(1-methylethyl)-,(3S,4S,7R)-(9CI)
• Synonyms: 1-Oxaspiro[2.5]octane,7-methyl-4-(1-methylethyl)-,(3S,4S,7R)-(9CI)
• CAS NO: 184178-86-7
• Molecular Formula: C₁₁H₂₀O
• Molecular Weight: 168.28
• Product Categories: ISOPROPYL
• Mol File: 184178-86-7.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-Oxaspiro[2.5]octane,7-methyl-4-(1-methylethyl)-,(3S,4S,7R)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Oxaspiro[2.5]octane,7-methyl-4-(1-methylethyl)-,(3S,4S,7R)-(9CI)(184178-86-7)
• EPA Substance Registry System: 1-Oxaspiro[2.5]octane,7-methyl-4-(1-methylethyl)-,(3S,4S,7R)-(9CI)(184178-86-7)

Safety Data

• Hazardous Substances Data: 184178-86-7(Hazardous Substances Data)

Upstream product

• 593-71-5 Chloroiodomethane 
• 10458-14-7 (2R,5S)-menthone 
• 1774-47-6 trimethylsulfoxonium iodide 
• 1196-31-2 (1R,4R)-(+)-isomenthone 
• 2181-42-2 trimethylsulphonium iodide 
• 119433-76-0 (1S,4R)-1-isopropyl-4-methyl-2-methylene-cyclohexane 

Downstream Products

• 338800-72-9 (1S,2S,5R)-1-[N,N-Bis(2-hydroxyethyl)aminomethyl]-1-hydroxy-5-methyl-2-(1-methylethyl)cyclohexane 
• 80482-64-0 (1S,2S,5R)-2-isopropyl-5-methylcyclohexanecarboxaldehyde 
• 80434-59-9 (1R,2S,5R)-2-isopropyl-5-methylcyclohexanecarboxaldehyde 
• 38618-25-6 (1S,2S,5R)-1,5-dimethyl-2-(1-methylethyl)cyclohexan-1-ol 

Relevant articles and documents

One-Pot Synthesis of N-tert-Butylsulfinylimines and Homoallylamine Derivatives from Epoxides

The reaction of epoxides with tert-butanesulfinamide in the presence of a Lewis acid, such as erbium triflate or boron trifluoride–diethyl ether, in THF as solvent, under microwave or thermal activation, produces N-tert-butylsulfinylimines in reasonable yields. Aromatic and gem-disubstituted and trisubstituted alkyl epoxides performed better than mono-alkyl-substituted compounds. After imine formation, a subsequent indium-promoted allylation can be carried out in the same reaction flask in a single synthetic operation leading to homoallylamine derivatives with generally high yields.

Synthesis and characterization of a new enantiopure hydroxylated phosphine, its rhodium(I) and (III) complexes and their performance in catalytic carbonylation

The enantiomerically pure hydroxylated phosphine (1S,2S,5R)-1-diphenylphosphinomethyl-2-isopropyl-5-methyl-cyclohexanol 3 was prepared in a two-step stereoselective process from the commercially available and low cost (-)-menthone. Reaction of this new li