18425-76-8

Upstream product

• 75347-10-3 potassium 2,3,4,6-tetra-O-acetylgluconasturtiin 
• 22818-69-5 (3-nitropropyl)benzene 
• 1197-50-8 (Z)-3-phenylpropionaldehyde oxime 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 40591-65-9 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl isothiouronium bromide 
• 637-59-2 1-Bromo-3-phenylpropane 
• 19879-84-6 tetraacetyl thioglucose 
• 19879-84-6 O²,O³,O⁴,O⁶-Tetraacetyl-1-thio-D-glucose 
• 130718-52-4 1-S-trityl-2,3,4,6-tetra-O-acetyl-1-thio-α-D-glucopyranose 
• 92691-83-3 2,3,4,6-tetra-O-acetyl-1-thio-α-D-glucopyranose 
• 130735-52-3 3-Phenyl-propionitrile N-oxide 
• 130796-16-6 Acetic acid (2R,3R,4S,5R,6R)-3,5-diacetoxy-2-acetoxymethyl-6-(N-hydroxy-3-phenyl-propionimidoylsulfanyl)-tetrahydro-pyran-4-yl ester 
• 75336-75-3 S-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-3-phenylpropanothiohydroximate 
• 75336-73-1 1-chloro-3-phenylpropanal oxime 

Downstream Products

• 82701-40-4 C₃₀H₆₁NO₆SSi₅ 

Relevant academic research and scientific papers

Improved Synthesis of Glucosinolates

Herein we describe an improved synthesis of glucosinolates, in which the quantity and cost of materials have been reduced by approximately an order of magnitude compared to typical literature procedures. This allowed us to produce multiple glucosinolates in 10-25 gram batches using vessel sizes no larger than 0.5 litres.

FIRST SYNTHESIS OF ALPHA GLUCOSINOLATES

A general synthesis of the alpha-anomers of naturally occurring glucosinolates is proposed.

Synthesis of glucosinolates

A high yielding synthesis of 2-phenethylglucosinolate is described. The method should also be directly applicable to most (if not all) other glucosinolates.