1843-03-4

Basic information

• Product Name: 1,1,3-TRIS(2-METHYL-4-HYDROXY-5-TERT-BUTYLPHENYL)BUTANE
• Synonyms: 1,1,3-TRIS(2-METHYL-4-HYDROXY-5-TERT-BUTYLPHENYL)BUTANE;1,1,3-TRIS-(2-TERT-BUTYL-4-HYDROXY-5-METHYLPHENYL)-BUTANE;1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylphenyl);4,4’,4’’-(1-methyl-1-propanyl-3-ylidene)tris(2-(1,1-dimethylethyl)-5-methylp;4,4’,4’’-(1-methyl-1-propanyl-3-ylidene)tris(6-tert-butyl-m-creso;4,4’,4’’-(1-methyl-1-propanyl-3-ylidene)tris[2-(1,1-dimethylethyl)-5-methyl-Phenol;gsy930;henol)
• CAS NO: 1843-03-4
• Molecular Formula: C₃₇H₅₂O₃
• Molecular Weight: 544.81
• EINECS: 217-420-7
• Product Categories: Industrial/Fine Chemicals;Organics
• Mol File: 1843-03-4.mol
• Article Data: 23

Chemical Properties

• Melting Point: 183-190 °C(lit.)
• Boiling Point: 578.54°C (rough estimate)
• Flash Point: 225 °F
• Appearance: /
• Density: 0.5g/cm3
• Vapor Pressure: 1.91E-15mmHg at 25°C
• Refractive Index: 1.5800 (estimate)
• PKA: 10.38±0.20(Predicted)
• Water Solubility: 0.02ng/L at 20℃
• CAS DataBase Reference: 1,1,3-TRIS(2-METHYL-4-HYDROXY-5-TERT-BUTYLPHENYL)BUTANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,3-TRIS(2-METHYL-4-HYDROXY-5-TERT-BUTYLPHENYL)BUTANE(1843-03-4)
• EPA Substance Registry System: 1,1,3-TRIS(2-METHYL-4-HYDROXY-5-TERT-BUTYLPHENYL)BUTANE(1843-03-4)

Safety Data

• WGK Germany: 1
• RTECS: SM1157000
• Hazardous Substances Data: 1843-03-4(Hazardous Substances Data)

Usage

Uses

Used in Plastics and Rubber Industry:
1,1,3-Tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane is used as a stabilizer for various resins such as polypropylene, polyethylene, polyvinyl chloride, ABS, and polyoxymethylene. It is particularly beneficial for light-colored rubber products due to its ability to prevent degradation and discoloration caused by oxidation.
Additionally, it is used as a synergistic antioxidant alongside DLTP, enhancing the overall stability and performance of the materials in which it is incorporated. This makes it a valuable component in the production of plastics and rubber goods that require resistance to heat, light, and oxygen-induced degradation.

Flammability and Explosibility

Nonflammable

InChI:InChI=1/C37H52O3/c1-21(25-18-29(35(5,6)7)32(38)15-22(25)2)14-28(26-19-30(36(8,9)10)33(39)16-23(26)3)27-20-31(37(11,12)13)34(40)17-24(27)4/h15-21,28,38-40H,14H2,1-13H3

Synthetic route

2,2,6,6-Tetramethyl-1-piperidinyloxy free radical (2564-83-2, 45842-10-2) + 1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane (1843-03-4) → C37H52O3*3C9H18NO

Conditions	Yield
In toluene	86%

(E)-3-[4-[6-(2-methylprop-2-enoyloxy)hexoxy]phenyl]prop-2-enoic acid (125274-23-9) + 1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane (1843-03-4) → CLM_007

Conditions	Yield
With benzotriazol-1-ol; N-(3-dimethylaminopropyl)-N-ethylcarbodiimide; triethylamine In N,N-dimethyl-formamide at 20℃; for 24h;	70%

1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane (1843-03-4) + dimethylchloromethylphosphine oxide (1638-75-1) → 1,1,3-tris(5'-tert-butyl-2'-methyl-4'-dimethylphosphinylmethyleneoxybenzene)butane (139613-06-2)

Conditions	Yield
With sodium hydroxide
With sodium 1) xylene, MeOH, 2) xylene, reflux, 8 h; Yield given. Multistep reaction;

1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane (1843-03-4) + N,N-dimethyl-formamide (68-12-2, 33513-42-7) → C40H52O6 (21982-27-4)

Conditions	Yield
With trichlorophosphate

2-(3,5-di-tert-butyl-4-hydroxyphenyl)propionyl chloride + 1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane (1843-03-4) → 1,1,3-tris[2-methyl-4-(3,5-di-tert-butyl-4-hydroxyphenylpropionyloxy)-5-tert-butylphenyl]butane

Conditions	Yield
With triethylamine In water; toluene

Downstream Products

• 139613-06-2 1,1,3-tris(5'-tert-butyl-2'-methyl-4'-dimethylphosphinylmethyleneoxybenzene)butane 
• 21982-27-4 C₄₀H₅₂O₆ 

Relevant articles and documents

COLOR DEVELOPING COMPOSITION CONTAINING MOLECULAR COMPOUND, AND RECORDING MATERIAL

Provided is a color-developing composition containing a molecular compound which has as a component compound a compound represented by formula (I) [wherein Y represents a C1-C12 hydrocarbon group which is chained or branched and saturated or unsaturated, or a C1-C8 hydrocarbon group which is chained or branched, saturated or unsaturated and has an ether or thioether bond; R1, R2, R3 and R4 each independently represent a C1-C6 alkyl group or C2-C6 alkenyl group; n, p, q and r each represents any integer of 0 to 4; and m represents any integer of 0 to 2]. Also provided is a recording material with a sufficient color-forming sensitivity, superior storage stability, and especially with an extremely little background fogging in a heat resistance test.

4-Formyl amino-n-methylpiperidine derivatives, the use thereof as stabilisers and organic material stabilised therewith

The present invention relates to 4-formylamino-N-methylpiperidine derivatives of the formula (I) where the variables are as defined in the Description, to a process for preparing these piperidine derivatives, to the use of these piperidine derivatives of the invention, or prepared according to the invention, for stabilizing organic material, in particular for stabilizing plastics or coating materials, and also to the use of these piperidine derivatives of the invention, or prepared according to the invention, as light stabilizers or stabilizers for wood surfaces. The present invention further relates to stabilized organic material which comprises these piperidine derivatives of the invention or prepared according to the invention.

Mixture of substances containing compounds with vinyl groups and stabilizers

A mixture contains one or more vinyl-containing compounds as component (A) and, as a further component, a stabilizer (B) which contains one or more readily volatile nitroxyl compounds as component (b1), one or more sparingly volatile nitroxyl compounds as component (b2), if required one or more aromatic nitro compounds as component (b3) and, if required, one or more iron compounds as component (b4).Stabilizers (B) contain the components (b1) and (b2), (b1) and (b2) and (b3), (b1) and (b2) and (b4), and (b1), (b2), (b3) and (b4), and the premature polymerization of vinyl-containing compounds during their purification or distillation is inhibited by a process in which a stabilizer (B) is added or the components of stabilizer (B) are added as individual substances or in at least two groups of the components.

4-acylaminopiperidin-N-oxyle

4-Acylaminopiperidine N-oxides Ia where A1 is hydrogen or an organic radical and B1 is a radical IIa STR1 where R1 -R4 are each C1 -C4 -alkyl and R1 and R2, on the one hand, and R3 and R4, on the other hand, may furthermore be bonded to form a 5-membered or 6-membered ring, R5 is H or C1 14 C4 -alkyl and R6 is H or C1 -C18 -alkyl, are used for stabilizing organic materials against the harmful effect of free radicals, particularly in the distillation of monomers which undergo free radical polymerization, especially styrene.

Phenolic compounds

A phenolic compound having formula (I): STR1 wherein X represents a chlorine atom or a methyl group, and a recording material comprising a coloress or light-colored leuco dye and the above phenolic compound serving as a color developer for the leuco dye are disclosed.

Substituted piperazines and polymeric compositions stabilized thereby

Substituted piperazines are stabilizers for synthetic polymeric materials normally subject to deterioration caused by ultraviolet light. The compounds are prepared by the alkylation reaction between a substituted piperazine dione and an organic halide followed by reduction with lithium aluminum hydride. Polymeric compsitions containing these stabilizers may also contain a hindered phenolic compound. A typical embodiment is 15,15'-dodecamethylene-bis(7,15-diazadispiro[5,1,5,3]hexadecane).

Piperidine derivatives

New 1- and 4-substituted piperidines are stabilizers for organic material. They are produced by reacting corresponding 1-substituted piperidinols with acid chlorides or corresponding 4-substituted piperidines with a compound introducing into the 1-position a residue.

Piperidine derivatives

New piperidine derivatives of 1,3-pyrimidine and 1,3,5-triazine are used as stabilizers for organic materials, especially for polymers.

Hydroxyaryl-tetramethyl-piperidines

New 4-(4'-hydroxyaryl)-2,2,6,6-tetramethyl-piperidines are used as stabilisers for organic materials, especially for polymers.

Substituted piperidin-4-ols

Disclosed are stabilized compositions comprising a polymer, especially polyolefines, and a minor proportion of a 1,2,2,6,6-pentasubstituted piperidin-4-ol. The new compositions possess good light stability.