18433-33-5

Upstream product

• 79470-05-6 ((C₆H₅)3P)2(Cl)(N₂)(H)IrFBF₃ 

Downstream Products

• 31690-54-7 C₃₆H₃₀ClIrP₂ 
• 66752-91-8 [Ir(η2-SCNMe2)Cl2(PPh3)2] 
• 100837-29-4 IrCl(HC(COC₆H₅)2)(P(C₆H₅)3)(PC₆H₄(C₆H₅)2) 
• 86288-19-9 IrCl(HC(COC₆H₅)2)(P(C₆H₅)3)(PC₆H₄(C₆H₅)2) 
• 86272-05-1 IrCl(HC(COC₆H₅)2)(P(C₆H₅)3)(PC₆H₄(C₆H₅)2)*0.5C₆H₅CH₃ 
• 894084-63-0 [IrH(Cl)(κ2(C,O)-CHCHCOOMe)(PPh3)2] 
• 17000-10-1 trans-trans-IrHCl₂(CO)(PPh₃)2 
• 100897-49-2 IrCl(H)(CO)(O₂CCF₃)(P(C₆H₅)3)2 
• 21007-05-6 Ir(H)(CO)(O₂CCF₃)2(P(C₆H₅)3)2 
• 894084-59-4 [IrH(Cl)(κ2(C,O)-C(Ph)CHC(Me)O)(PPh3)2] 
• 898555-64-1 trans-[Ir(triphenylphosphine)2Cl(η2-Me3SiCCCO2Et)] 

Relevant academic research and scientific papers

Chloro-, Methyl- und Hydrido-Iridiumkomplexe mit Ph2CN2 und anderen Diazoalkan-Liganden

Diazoalkane iridium complexes of the general composition trans- (6, 7), trans- (9, 10, 14), trans-iPr3)2> (16, 17) and iPr3)2> (19-21) were prepared from tra

METALLORGANISCHE LEWIS-SAEUREN. XXIII. HYDRIDO-IRIDIUM(III)-KOMPLEXE MIT SCHWACH KOORDINIERTEN ANIONEN UND DISTICKSTOFF ALS ABGANGSGRUPPEN

The oxidative addition of HBF4 and C4F9SO3H to the nitrogen complex trans-(Ph3P)2Ir(N2)Cl gives the hydrido iridium(III) complexes (Ph3P)2(N2)(Cl)Ir(H)X (X-=FBF3-, OSO2C4F9-) in which the two excellent leaving groups(X- and N2) can be successively substituted by weak and strong donors (H2O, CH3OH, CH3COCH3, THF, CH3CN, CO, C2H4, PPh3; dithiocarbamate, valinate). (Ph3P)2(L)(Cl)Ir(H)FBF3 (L=CO, N2) catalyze the isomerization of 1,2-diphenyl- and phenyloxirane to diphenyl and phenyl acetaldehyde, respectively.