79470-05-6

Upstream product

• 15695-36-0 trans-{IrCl(N₂)(PPh₃)2} 

Downstream Products

• 99626-35-4 chloro-hydrido-9-methylguanine-bis-(triphenylphosphine)-iridium(III)-tetrafluoroborate 
• 110311-26-7 chloro-dinitrogen-ethylene-hydrido-bis(triphenylphosphine)-iridium(III) tetrafluoroborate 
• 79292-52-7 chloro(N,N-diethyldithiocarbamato)hydridobis(triphenylphosphine)iridium(III) 
• 110311-20-1 chloro(dinitrogen)hydridobis(triphenylphosphine)(tetrahydrofuran)iridium(III) tetrafluoroborate 
• 110311-24-5 carbonyl-chloro-dinitrogen-hydrido-bis(triphenylphosphine)-iridium(III) tetrafluoroborate 
• 110328-93-3 bis(acetone)chlorohydridobis(triphenylphosphine)iridium(III) tetrafluoroborate 
• 110311-16-5 chloro-dinitrogen-hydrido-methanol-bis(triphenylphosphine)-iridium(III) tetrafluoroborate 
• 110311-14-3 aqua-chloro-dinitrogen-hydrido-bis(triphenylphosphine)-iridium(III)-tetrafluoroborate 
• 15695-36-0 trans-{IrCl(N₂)(PPh₃)2} 

Relevant academic research and scientific papers

METALLORGANISCHE LEWIS-SAEUREN. XXIII. HYDRIDO-IRIDIUM(III)-KOMPLEXE MIT SCHWACH KOORDINIERTEN ANIONEN UND DISTICKSTOFF ALS ABGANGSGRUPPEN

The oxidative addition of HBF4 and C4F9SO3H to the nitrogen complex trans-(Ph3P)2Ir(N2)Cl gives the hydrido iridium(III) complexes (Ph3P)2(N2)(Cl)Ir(H)X (X-=FBF3-, OSO2C4F9-) in which the two excellent leaving groups(X- and N2) can be successively substituted by weak and strong donors (H2O, CH3OH, CH3COCH3, THF, CH3CN, CO, C2H4, PPh3; dithiocarbamate, valinate). (Ph3P)2(L)(Cl)Ir(H)FBF3 (L=CO, N2) catalyze the isomerization of 1,2-diphenyl- and phenyloxirane to diphenyl and phenyl acetaldehyde, respectively.