18435-45-5

Basic information

• Product Name: 1-Nonadecene
• Synonyms: NSC 77135
• CAS NO: 18435-45-5
• Molecular Formula: C19H38
• Molecular Weight: 0
• EINECS: 242-313-7
• Mol File: 18435-45-5.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 328°Cat760mmHg
• Flash Point: 163.7°C
• Appearance: /
• Density: 0.79g/cm³
• Vapor Pressure: 0.000373mmHg at 25°C
• Refractive Index: 1.445
• CAS DataBase Reference: 1-Nonadecene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Nonadecene(18435-45-5)
• EPA Substance Registry System: 1-Nonadecene(18435-45-5)

Safety Data

• Hazardous Substances Data: 18435-45-5(Hazardous Substances Data)

Usage

General Description

1-Nonadecene is a chemical compound that belongs to the class of organic compounds known as alkenes. It's essentially a hydrocarbon which has 19 carbon atoms, making it a relatively long-chain compound. These substances are distinguished by the presence of one or more carbon-carbon double bonds. Its molecular formula is C19H38 and it is often used in manufacturing, particularly in the production of detergents and other cleaning products. Its structure gives it hydrophobic properties, making it excellent for uses associated with repelling water. It is also used within the perfume and flavoring industry for its ability to lock in and maintain fragrance smells.

InChI:InChI=1/C19H38/c1-3-5-7-9-11-13-15-17-19-18-16-14-12-10-8-6-4-2/h3H,1,4-19H2,2H3

Upstream product

• 872-26-4 hexadecylmagnesium bromide 
• 106-95-6 allyl bromide 
• 112-89-0 1-Bromooctadecane 
• 591-87-7 Allyl acetate 
• 112-82-3 hexadecanyl bromide 
• 506-30-9 Arachidic acid 
• 62155-12-8 1-methylsulfanyl-nonadecane 
• 74-88-4 methyl iodide 
• 112-61-8 Methyl stearate 

Downstream Products

• 26186-01-6 nonadec-1-yne 
• 133281-17-1 Carbonic acid 4-heptadecyl-[1,3]dioxolan-2-ylmethyl ester phenyl ester 
• 133281-03-5 5-Heptadecyl-2-benzyloxymethyl-1,3-dioxolane 
• 22725-63-9 1-triacosanal 
• 593-50-0 melissyl alcohol 
• 4443-56-5 2-cyclohexyl-eicosane 
• 595557-03-2 (1E)-1-(vinylsulfonyl)nonadec-1-ene 
• 39516-65-9 2-hydroxy-1-nonadecanol 

Relevant articles and documents

An Engineered Self-Sufficient Biocatalyst Enables Scalable Production of Linear α-Olefins from Carboxylic Acids

Fusing the decarboxylase OleTJE and the reductase domain of P450BM3 creates a self-sufficient protein, OleT-BM3R, which is able to efficiently catalyze oxidative decarboxylation of carboxylic acids into linear α-olefins (LAOs) under mild aqueous conditions using O2 as the oxidant and NADPH as the electron donor. The compatible electron transfer system installed in the fusion protein not only eliminates the need for auxiliary redox partners, but also results in boosted decarboxylation reactivity and broad substrate scope. Coupled with the phosphite dehydrogenase-based NADPH regeneration system, this enzymatic reaction proceeds with improved product titers of up to 2.51 g L-1 and volumetric productivities of up to 209.2 mg L-1 h-1 at low catalyst loadings (～0.02 mol%). With its stability and scalability, this self-sufficient biocatalyst offers a nature-friendly approach to deliver LAOs.

Iron-catalyzed decarbonylation reaction of aliphatic carboxylic acids leading to α-olefins

The catalytic decarbonylation reaction of aliphatic carboxylic acids can be carried out in the presence of an iron complex, and it proceeds smoothly to give α-olefins with high selectivity. The Royal Society of Chemistry 2012.

Efficient iridium-catalyzed decarbonylation reaction of aliphatic carboxylic acids leading to internal or terminal alkenes

Vaska's complex, IrCl(CO)(PPh3)2, when combined with KI as an additive, served as an excellent catalyst for the decarbonylation of long-chain aliphatic carboxylic acids to give internal alkenes with high selectivity. On combination with KI and Ac2O as additives under controlled temperatures, decarbonylation proceeded to give terminal alkenes with high selectivity.