184355-40-6

Upstream product

• 959785-70-7 4-methyl-2-thiopheneboronic anhydride 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 616-44-4 3-Methylthiophene 
• 696-62-8 para-iodoanisole 

Downstream Products

• 479077-56-0 1-[3-methyl-5-(p-methoxyphenyl)-2-thienyl]perfluorocyclopentene 
• 676258-36-9 1-[3-methyl-5-(p-methoxyphenyl)-2-thienyl]-2-[2-methyl-5-(p-methoxyphenyl)-3-thienyl]perfluorocyclopentene 
• 184355-37-1 1,2-bis[3-methyl-5-(p-methoxyphenyl)-2-thienyl]perfluorocyclopentene 

Relevant academic research and scientific papers

C-H arylation of 3-substituted thiophene with regioselective deprotonation by tmpMgCl·LiCl and transition metal catalyzed cross coupling

The reaction of 3-hexylthiophene with Knochel-Hauser base (TMPMgCl·LiCl) induced the metalation at the 5-position of the thiophene ring selectively. Following addition of several aryl halides in the presence of a nickel or palladium catalyst afforded regi

Selective protodeboronation: synthesis of 4-methyl-2-thiopheneboronic anhydride and demonstration of its utility in Suzuki-Miyaura reactions

An efficient synthesis of 4-methyl-2-thiopheneboronic anhydride is reported. Regioselective lithiation of 3-methylthiophene followed by reaction with triisopropylborate and hydrolysis provides a 92:8 ratio of 4-methyl-2-thiopheneboronic acid (1) and regio

Substituent effect on the photochromic reactivity of bis(2-thienyl)perfluorocyclopentenes

Substituent effect on the photochromic reactivity of bis(2-thienyl)perfluorocyclopentenes was examined. Introduction of phenyl groups having electron-donating substituents on the para-position of the phenyl ring to the 5-position of the thiophene rings shifted the absorption bands of the open-ring isomers to longer wavelengths and reduced the quantum yield of the cyclization reactions. The substitution with p-(N,N-diethylamino)phenyl groups prohibited the cyclization reaction. The absorption spectra of the closed-ring isomers were not influenced by the substitution.