18449-03-1

Usage

Uses

Used in Coordination Chemistry:
(6Z)-2-methoxy-6-[(phenylamino)methylidene]cyclohexa-2,4-dien-1-one cobalt (2:1) is used as a coordination compound for the study of metal-ligand interactions and the development of new coordination complexes with potential applications in various fields.
Used in Catalysis:
(6Z)-2-methoxy-6-[(phenylamino)methylidene]cyclohexa-2,4-dien-1-one cobalt (2:1) is used as a catalyst in organic synthesis for facilitating various chemical reactions, such as oxidation, reduction, and coupling reactions, due to its ability to undergo redox reactions and stabilize transition states.
Used in Research and Development:
(6Z)-2-methoxy-6-[(phenylamino)methylidene]cyclohexa-2,4-dien-1-one cobalt (2:1) is used as a research compound for investigating its chemical and physical properties, as well as exploring its potential applications in various industries, such as pharmaceuticals, materials science, and environmental remediation.

Upstream product

• 55516-89-7 chlorotris(trimethylphosphane)cobalt(I) 
• 3117-63-3 (3-methoxy-N-salicylidene)aniline 

Relevant academic research and scientific papers

Investigating the solid state hosting abilities of homo- and hetero-valent [Co7] metallocalix[6]arenes

A family of homo-valent [Co(ii)7(OH)6(L 1)6](NO3)2 (1), [(MeOH) 2?Co(ii)7(OH)6(L1) 6](NO3)2 (2) (where L1H = 2-iminomethyl-6-methoxyphenol) and hetero-valent [(NO3) 2?Co(iii)Co(ii)6(OH)6(L2) 6](NO3)·3MeCN (4) (where L2H = 2-iminophenyl-6-methoxyphenol) complexes possess metallic skeletons describing planar hexagonal discs. Their organic exteriors form double-bowl shaped topologies, and coupled with their 3-D connectivity, this results in the formation of molecular cavities in the solid state. These confined spaces are shown to behave as host units in the solid state for guests including solvent molecules and charge balancing counter anions. Magnetic susceptibility measurements on 2 and 4 reveal weak ferro- and ferrimagnetism, respectively. The utilisation of other Co(ii) salt precursors gives rise to entirely different species including the mononuclear and trinuclear complexes [Co(ii)(L 2)2] (5) and [Co(iii)2Na(i)1(L 3)6](BF4) (6) (where L3H = 2-iminomethyl-4-bromo-6-methoxyphenol).

Reactions of trimethylphosphane-supported cobalt complexes with salicylaldimines - Formation and structures of cobalt compounds containing salicylaldiminato [N:O] ligands

The reactions of low-valent cobalt complexes CoMe(PMe3) 4, CoCl(PMe3)3 and Co(PMe3) 4 with salicylaldimines are described to give tetrahedral complexes 7-12, an octahedral complex 13 and a π-coordinated imine complex 15. The crystal structures of 13 and 15 are reported. The formation and likely mechanisms are discussed. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.