3117-63-3

Usage

InChI:InChI=1/C14H13NO2/c1-17-13-9-5-6-11(14(13)16)10-15-12-7-3-2-4-8-12/h2-10,15H,1H3/b11-10+

Upstream product

• 148-53-8 3-methoxy-2-hydroxybenzaldehyde 
• 62-53-3 aniline 
• 98-95-3 nitrobenzene 

Downstream Products

• 18449-03-1 bis(3-methoxy-N-phenylsalicylaldiminato)cobalt(II) 
• 17668-28-9 bis(2-methoxy-6-((phenylimino)methyl)phenolato)copper(II) 

Relevant academic research and scientific papers

The effect of ligand design on the structural and photophysical properties of Nd(III) complexes with Schiff bases of the [(phenylimino)methyl]phenol-type

Three mononuclear Nd(III) complexes [Nd(HL1)2(NO3)3] (1, HL1=2-methoxy-6-[(E)-(phenylimino)methyl]phenol), [Nd(HL2)3(NO3)3] (2, HL2=5-methoxy-2-[

Palladium (II) complexes based on Schiff base ligands derived from ortho-vanillin; synthesis, characterization and cytotoxic studies

6-Methoxy-2-[(E)-Aryliminomethyl]-phenol (Aryl = Phenyl; 2,6-dimethyl; 2,6-diisopropylphenyl; 2,6-dichlorophenyl), comprising L1–L4 ligands, and palladium complexes [Pd(Ln)2, n = 1–4] have been synthesized. The

Vibrational analysis and physical property studies of 6-Methoxy-2-[(E)-phenyliminomethyl]-phenol in the THz, IR and UV–visible spectral regions

Bulk single crystals of 6-Methoxy-2-[(E)-phenyliminomethyl]phenol were grown after preparing the material by Schiff base condensation of ortho-vanillin alternatively called 2-hydroxy-3-methoxybenzaldehyde and aniline. The three dimensional molecular and c

Catalytic investigation of Pd(II) complexes over Heck–Mizoroki reaction: Tailored synthesis, characterization and density functional theory

Tailored reaction of Schiff base ligands with palladium(II) chloride and imidazole afford three complexes of formula [Pd(II)(L)(imdz)2]Cl, which are L = 2-((E)-(p-lylimino)methyl)-6-methoxyphenol (complex 1), 2-methoxy-6-((E)-(phenylimine)methyl)phenol (complex 2) and 2-((E)-(4-chlorophenyl-imino)methyl)-6-methoxyphenol (complex 3). Compounds were characterized with elemental analysis, molar conductance, electronic spectroscopy, ESI-MS, FT-IR, TGA, 1H-NMR and 13C-NMR. Molecular structure and different quantum chemical parameters were calculated using the B3LYP basis set of density functional theory with the standard 6-311+G (d, 2p) level. The catalytic potential of 1-3 was examined over Heck-Mizoroki reaction and found in order of 1 > 2 > 3.

The Direct Synthesis of Imines, Benzimidazoles and Quinoxalines from Nitroarenes and Carbonyl Compounds by Selective Nitroarene Hydrogenation Employing a Reusable Iron Catalyst

The “replacement” of noble metals by earth abundant metals is a desirable aim in catalysis and a possible way of conserving rare elements. The “replacement” is especially attractive if novel selectivity patterns are observed permitting the development of novel coupling reactions. Herein, we report on a novel, robust and reusable iron catalyst, which permits the selective hydrogenation of nitroarenes in the presence of hydrogenation-sensitive functional groups. Based on the selectivity pattern observed, the direct iron-catalyzed synthesis of imines and benzimidazoles from nitroarenes and aldehydes becomes feasible. In addition, we introduce the direct synthesis of quinoxalines from nitroarenes and diketones applying our catalyst.

Synthesis, Characterization and Fluorescence Properties of Zn(II) and Cu(II) Complexes: DNA Binding Study of Zn(II) Complex

Zinc(II) and copper(II) complexes containing Schiff base, 2- methoxy-6((E)-(phenylimino) methyl) phenol ligand (HL) were synthesized and characterized by elemental analysis, IR, NMR, and single crystal X-ray diffraction technique. The fluorescence propert

A Reusable Co Catalyst for the Selective Hydrogenation of Functionalized Nitroarenes and the Direct Synthesis of Imines and Benzimidazoles from Nitroarenes and Aldehydes

The use of abundantly available transition metals in reactions that have been preferentially mediated by rare noble metals, for example, hydrogenations, is a desirable aim in catalysis and an attractive strategy for element conservation. The observation of novel selectivity patterns with such inexpensive metal catalysts is especially appealing. Herein, we report a novel, robust, and reusable cobalt catalyst that permits the selective hydrogenation of nitroarenes in the presence of highly hydrogenation-sensitive functional groups, as well as the direct synthesis of imines from nitroarenes and aldehydes or ketones in the presence of such substituents. Furthermore, we introduce the first base-metal-mediated direct synthesis of benzimidazoles from nitroarenes and aldehydes. Functional groups that are easy to hydrogenate are again well tolerated.

Synthesis and characterization of 3d and 4f metal complexes of Schiff base ligands

Square planar complexes of monomeric [Cu(L1)2] (1) and [Ni(L1)2] (2) (where L1 is C20H24NO 2) are isolated through the use of Schiff base ligands and characterized by X-ray diffraction, UV-Vis, electr

Zinc(II) and mercury(II) complexes with Schiff bases: Syntheses, spectral, and structural characterization

Schiff bases o-vanilidene-1-aminobenzene (HL1) and o-vanilidene-2-methyl-1-aminobenzene (HL2) lead to the formation of mono-and bis-[(Cl)Zn(L1)] (1), [(Cl)Zn(L2)] (2), [(Cl)Hg(L1)] (3), [(Cl)Hg(L

Sulfonic acid supported on hydroxyapatite-encapsulated-γ-Fe 2O3 nanocrystallites as a magnetically separable catalyst for one-pot reductive amination of carbonyl compounds

A novel, environmentally friendly procedure has been developed for the preparation of secondary or tertiary amines by one-pot reductive amination of carbonyl compounds using sodium borohydride in the presence of a magnetically recoverable sulfonic acid supported on hydroxyapatite-encapsulated-γ- Fe2O3 [γ-Fe2O3@HAP-SO 3H] at room temperature. The catalyst was easily separated from the reaction mixture by applying an external magnet and reused for six cycles without significant loss of catalytic activity.