184680-03-3Relevant articles and documents
Oxidative fragmentation of 1-aryl-1-cycloalkenes using cerium(IV) ammonium nitrate (CAN): Some novel observations
Nair, Vijay,Panicker, Sreeletha B,Thomas, Siji,Santhi,Mathai, Sindhu
, p. 3229 - 3234 (2002)
1-Phenyl-1-cycloalkenes undergo oxidative fragmentation in presence of CAN in methanol, affording 1,n-dicarbonyl compounds as the major products along with 1,2-dimethoxycycloalkanes. The reaction under deoxygenated conditions afforded the latter in good yields. In the presence of azide ion, fragmentation leading to the corresponding cyanoketones was observed whereas with sulfinate only the 1-methoxy-2-sulfonyl cycloalkanes were formed.
Studies toward soraphen A: An aldol-metathesis avenue to the macrocyclic framework
Vincent, Guillaume,Mansfield, Darren J.,Vors, Jean-Pierre,Ciufolini, Marco A.
, p. 2791 - 2794 (2007/10/03)
We describe a convergent approach to soraphen A, 1, that involves coupling of two fragments by an aldol condensation-olefin metathesis sequence. This route permits rapid access to congeners of 1.
CAN mediated fragmentation of 1-phenylcycloalkenes: Synthesis of monoacetals of 1,n-dicarbonyl compounds
Nair, Vijay,Panicker, Sreeletha B.
, p. 563 - 564 (2007/10/03)
Phenylcycloalkenes undergo facile oxidative fragmentation in presence of CAN in methanol giving ketoacetals of 1,n-dicarbonyl compounds.
A new approach to arylaliphatic 1,5-, 1,6-, and 1,7-dicarbonyl compounds and their monoacetals based on direct anodic oxidation of 1-phenyl- and benzo[c]cycloalkenes
Ogibin,Ilovaisky,Nikishin
, p. 1939 - 1941 (2007/10/03)
A new simple approach to ω-benzoylalkanals, 2-(ω-formylalkyl)benzaldehydes, and their monoacetals was developed based on direct anodic oxidation of 1-phenylcycloalkenes and benzo[c]cycloalkenes in methanol followed by acid hydrolysis of the electrolysis p
