18475-11-1

Upstream product

• 62-53-3 aniline 
• 14740-77-3 pentacarbonyl(pyridine)chromium⁽⁰⁾ 
• 30633-04-6 (CO)5CrS(C₂H₅)Sn(CH₃)3 
• 199620-14-9 chromium⁽⁰⁾ hexacarbonyl 

Downstream Products

• 15134-57-3 (cyclohexylamine)chromium pentacarbonyl 
• 29742-98-1 ((C₆H₅)3As)Cr(CO)5 
• 25934-56-9 (CO)5Cr*As(C₆H₁₁)3=(CO)5CrAs(C₆H₁₁)3 
• 22750-29-4 (CO)5CrS{Ge(CH₃)3}(C₆H₅) 
• 15134-53-9 (CO)5Cr{NCN(C₆H₁₁)2} 
• 14568-32-2 (CO)5CrOS(C₆H₅)2 
• 21974-31-2 (CO)5Cr{o-(CH₃)2AsC₆H₄N(CH₃)2} 
• 29985-15-7 ((C₆H₅)3Sb)Cr(CO)5 
• 31172-87-9 (CO)5CrSP(C₆H₅)2CH₃ 
• 31172-86-8 (CO)5Cr*S(CH₃)Au(P(C₆H₅)3)=(CO)5CrS(CH₃)AuP(C₆H₅)3 
• 15096-64-7 pentacarbonyl[(N-cyanimino)triphenylphosphorane]chromium 
• 22750-30-7 (CO)5CrS{Sn(CH₃)3}(C₆H₅) 
• 31172-84-6 (CO)5CrS(CH₃)P(C₆H₅)2 
• 14917-12-5 triphenylphosphine chromium pentacarbonyl 

Relevant academic research and scientific papers

REAKTIONEN AN KOMPLEXGEBUNDENEN LIGANDED. XXXVI. SYNTHESE UND OXIDATIONSVERHALTEN VON M(CO)5-KOMPLEXEN (M = Cr, Mo, W) MIT AMIN- UND BENZOCHINONDIIMIN-LIGANDEN

The oxidation of yellow Cr(CO)5NH2R complexes (NH2R = aniline, m-toluidine, 3,5-xylidine, m-anisidine) with Pbac4 gives deep blue to deep purple coloured compounds, which have been identified as the respective complexes.Oxidation of the p-phenylenediamine complex yields , which is also deep blue.The binuclear blue complex 2HN=C6H4=NC6H5> is obtained by treating Cr(CO)5THF with the free ligand in THF/hexane; it dissociates rapidly in acetone to form and Cr(CO)5.Analogous Mo(CO)5 and W(CO)5 complexes could not be obtained.The oxidation of W(CO)5(m-anisidine)> by I2 yields 2.All the compounds were characterized by spectroscopic methods as well as by elemental analysis.