184764-89-4Relevant academic research and scientific papers
(Isocyanide)gold(I) thiosalicylates: Supramolecular assembly based on both auriophilic and hydrogen bonding
Schneider, Wolfgang,Bauer, Andreas,Schmidbaur, Hubert
, p. 5445 - 5446 (1996)
Reaction of (RNC)AuCl [R = tert-butyl (1a), mesityl (1b)] with sodium thiosalicylate in the two-phase system water / dichloromethane gives high yields of the corresponding (isocyanide)gold(I) thiosalicylates (2a,b). The solid-state structures of 2a,b have been determined by X-ray diffraction studies. The supramolecular structure of both compounds is governed by Au-Au interactions [2a, Au-Au 3.157(2) ?; 2b, Au-Au 3.3186(5) ?] and hydrogen bonding through the carboxylic acid groups.
