18483-97-1Relevant academic research and scientific papers
An efficient zirconia catalyst for solvent free tetrahydropyranylation of alcohols and phenols
Reddy, Benjaram M.,Sreekanth, Pavani M.
, p. 3561 - 3564 (2002)
Alcohols and phenols are tetrahydropyranylated in the presence of sulfated zirconia catalyst in good to excellent yields under solvent free conditions.
Introduction of a New Ionic Liquid Catalyst for the Trimethylsilyl and Tetrahydropyranyl Protection of Alcohols
Shirini, Farhad,Abedini, Masoumeh,Mahmoodi, Nosratollah,Biglari, Mohammad,Safarpoor Nikoo Langrudi, Mohaddeseh
, p. 1912 - 1921 (2015/12/12)
1,1'-Disulfo-[2,2'-bipyridine]-1,1'-hydrogen sulfate, BiPy(SO3H)2(HSO4)2, is prepared and identified as a new ionic liquid. This reagent was used for the promotion of the chemoselective trimethylsilyl and tetrahydropyranyl protection of alcohols. All reactions were performed under mild reaction conditions in high to excellent yields. Ease of the preparation of the heterogeneous catalyst, simplicity and easy work-up procedure, high reaction rates, and recyclability and reusability of the catalyst are the main advantages of this method.
Short communication: Catalytic tetrahydropyranylation of phenols and alcohols using vanadium(V)-substituted polyoxomolybdates
Gharib, Ali,Jahangir, Manouchehr
experimental part, p. 287 - 296 (2012/05/20)
Alcohols and phenols were tetrahydropyranylated in the presence of H 7[PMo8V4O40] in good to excellent yields in acetonitrile and under solventfree reaction conditions. A mild and convenient method for the formation and deprotection of ethers (THP ethers) is described. The formation of THP ethers from the corresponding alcohols was accomplished in the presence of acid-sensitive functional groups.
Mild and efficient chemoselective tetrahydropyranylation of alcohols using bronsted acidic ionic liquid as catalyst under solvent-free conditions
Hajipour, Abdol R.,Nasresfahani, Zahra
experimental part, p. 1995 - 2006 (2012/06/04)
A straightforward and efficient method for preparation of morpholinium bisulfate ([mroH]HSO4) as a novel acidic ionic liquid is reported. The application of this efficient and inexpensive acidic ionic liquid catalyst for tetrahydropyranylation of alcohols under mild and solvent-free conditions at room was investigated.
Tetrahydropyranylation of alcohols under solvent-free conditions
Hajipour, Abdol R.,Kargosha, Majid,Ruoho, Arnold E.
experimental part, p. 1084 - 1091 (2009/09/08)
A green, efficient, and large-scale method for tetrahydropyranylation of alcohols in the presence of a catalytic amount of pyridinium chloride at room temperature under solvent-free conditions is reported. Copyright Taylor & Francis Group, LLC.
Simple and facile tetrahydropyranylation of alcohols by use of catalytic amounts of benzyltriphenylphosphonium tribromide
Hajipour,Pourmousavi,Ruoho
, p. 2889 - 2894 (2007/10/03)
An efficient and mild system for protection of a variety of alcohols with 3,4-dihydro-2H-pyran (DHP) in the presence of catalytic amounts of benzyltriphenyl-phosphonium tribromide (BTPTB) (1) gives the corresponding tetrahydropyan ethers (ROTHP) in dichloromethane. The experimental procedure is simple, and the products are straightforwardly isolated in high to excellent yields. Copyright Taylor & Francis, Inc.
Potassium dodecatangestocobaltate trihydrate (K5CoW12O40·3H2O): A mild and efficient catalyst for the tetrahydropyranylation of alcohols and their detetrahydropyranylation
Habibi, Mohammad H.,Tangestaninejad, Shahram,Mohammadpoor-Baltork, Iraj,Mirkhani, Valiollah,Yadollahi, Bahram
, p. 2851 - 2853 (2007/10/03)
A simple, mild and effective method for tetrahydropyranylation of a variety of alcohols and cleavage of their tetrahydropyranyl ethers at ambient temperature in the presence of K5CoW12O40·3H2O as the catalyst with high turnovers is described.
