185038-94-2Relevant academic research and scientific papers
Nickel-Catalyzed, Regio- and Enantioselective Benzylic Alkenylation of Olefins with Alkenyl Bromide
Liu, Jiandong,Gong, Hegui,Zhu, Shaolin
supporting information, p. 4060 - 4064 (2020/12/25)
A NiH-catalyzed migratory hydroalkenylation reaction of olefins with alkenyl bromides has been developed, affording benzylic alkenylation products with high yields and excellent chemoselectivity. The mild conditions of the reaction preclude olefinic products from undergoing further isomerization or subsequent alkenylation. Catalytic enantioselective hydroalkenylation of styrenes was achieved by using a chiral bisoxazoline ligand.
Nickel-Catalyzed Reductive Cross-Coupling of Vinyl Bromides with Unactivated Alkyl Halides
Gu, Jun,Qiu, Canbin,Lu, Wenbin,Qian, Qun,Lin, Kunhua,Gong, Hegui
supporting information, p. 1867 - 1873 (2017/04/06)
The use of pyridine as the sole ligand for the reductive vinylation of unactivated secondary alkyl halides under Ni-catalyzed conditions has been developed. Both alkyl- and aryl-substituted vinyl bromides are suitable, in which alkyl-decorated α-alkenyl bromides resulted in the α-products in good results.
New polymer-supported organosilicon reagents
Fauvel, Anne,Deleuze, Herve,Landais, Yannick
, p. 3900 - 3910 (2007/10/03)
New polymer-supported organosilanes have been prepared using two different strategies. These involved the synthesis of soluble and insoluble supports through the copolymerization of styrene and monomers containing a thiophene ring. Selective metallation o
