18511-64-3Relevant academic research and scientific papers
Mild and efficient desulfurization of thiiranes with MoCl5/Zn system
Lee, Yeong Jin,Shin, Jeong Won,Yoo, Byung Woo
, (2021/11/10)
Desulfurization of a variety of thiiranes to alkenes occurs chemoselectively in high yields upon treatment with MoCl5/Zn system under mild conditions. The new methodology demonstrates high functional group tolerance toward chloro, bromo, fluoro, methoxy, ester, ether and keto groups.
Selective and efficient desulfurization of thiiranes with Mo(CO)6
Yoo, Byung Woo,Kim, Jung Youn
, p. 13 - 18 (2019/08/26)
Mo(CO)6 converts a broad range of thiiranes to the corresponding alkenes in high yields under neutral conditions. It has been found that this protocol is chemoselective and tolerates a variety of functional groups such as chloro, bromo, fluoro, ester, methoxy, ether and keto.
Isolation of the key intermediates in the catalyst-free conversion of oxiranes to thiiranes in water at ambient temperature
Kleiner, Christian M.,Horst, Luise,Wuertele, Christian,Wende, Raffael,Schreiner, Peter R.
supporting information; experimental part, p. 1397 - 1403 (2009/12/04)
Herein we shed light on the mechanism of the reaction of epoxides with ammonium thiocyanate to give the corresponding thiiranes in water, and we present a computational mechanistic model for this highly useful reaction.
NOVEL COMPOUNDS AS CANNABINOID RECEPTOR LIGANDS AND USES THEREOF
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Page/Page column 21, (2011/05/18)
The present invention relates to thiazolidinylidene containing compounds of formula (I) wherein R1, R2, R3, R4, R5, R6, and X are as defined in the specification, compositions comprising su
