185122-63-8

Basic information

• Product Name: 5-BROMO-1-INDANONE OXIME
• Synonyms: 5-BROMO-1-INDANONE OXIME
• CAS NO: 185122-63-8
• Molecular Formula: C₉H₈BrNO
• Molecular Weight: 226.06992
• Mol File: 185122-63-8.mol
• Article Data: 19

Chemical Properties

• Boiling Point: 346.5±41.0 °C(Predicted)
• Appearance: /
• Density: 1.67±0.1 g/cm3(Predicted)
• PKA: 11.12±0.20(Predicted)
• CAS DataBase Reference: 5-BROMO-1-INDANONE OXIME(CAS DataBase Reference)
• NIST Chemistry Reference: 5-BROMO-1-INDANONE OXIME(185122-63-8)
• EPA Substance Registry System: 5-BROMO-1-INDANONE OXIME(185122-63-8)

Safety Data

• Hazardous Substances Data: 185122-63-8(Hazardous Substances Data)

Usage

General Description

5-Bromo-1-indanone oxime is a chemical compound with the molecular formula C9H8BrNO and a molar mass of 222.07 g/mol. It is a white to yellow crystalline solid that is primarily used in organic synthesis and research. The oxime functionality of this compound makes it a versatile building block for the synthesis of various organic compounds, including pharmaceuticals. Its bromo and indanone moieties also give it unique reactivity and applications. 5-Bromo-1-indanone oxime is commonly used as a reagent in the preparation of biologically active compounds and in the study of organic reaction mechanisms. Its properties and applications make it a valuable tool in the field of organic chemistry.

Upstream product

• 31736-73-9 4-bromophenyl 2-chloroethyl ketone 
• 108-86-1 bromobenzene 
• 34598-49-7 5-Bromo-1-indanone 

Downstream Products

• 1199829-02-1 ethyl 1-((1-(benzyloxycarbonylamino)-2,3-dihydro-1H-inden-5-yl)methyl)-3-(trifluoromethyl)-1H-pyrazole-4-carboxylate 
• 1199828-95-9 N-(5-((4-(hydroxymethyl)-3-(trifluoromethyl)-1H-pyrazol-1-yl)methyl)-2,3-dihydro-1H-inden-1-yl)-2-methoxybenzenesulfonamide 
• 1199829-04-3 benzyl 5-((4-(hydroxymethyl)-3-(trifluoromethyl)-1H-pyrazol-1-yl)methyl)-2,3-dihydro-1H-inden-1-ylcarbamate 
• 1199828-99-3 methyl 1-(benzyloxycarbonylamino)-2,3-dihydro-1H-indene-5-carboxylate 
• 1251457-86-9 benzyl 5-(chloromethyl)-2,3-dihydro-1H-inden-1-ylcarbamate 
• 1199829-00-9 benzyl 5-(hydroxymethyl)-2,3-dihydro-1H-inden-1-ylcarbamate 
• 1199828-97-1 benzyl 5-bromo-2,3-dihydro-1H-inden-1-ylcarbamate 
• 1555862-60-6 5-[3-[3,5-bis(trifluoromethyl)phenyl]-3-(trifluoromethyl)pyrrolidin-1-yl]indan-1-amine 
• 1187512-62-4 N-[5-[3-(3,5-dichlorophenyl)-3-(trifluoromethyl)-2,4-dihydropyrrol-5-yl]indan-1-yl]acetamide 
• 1187196-68-4 tert-butyl N-[5-[3-(3,5-dichlorophenyl)-3-(trifluoromethyl)-2.4-dihydropyrrol-5-yl]indan-1-yl]carbamate 
• 1455457-34-7 N-(5-{3-[3,5-bis(trifluoromethyl)phenyl]-2-hydroxy-3-(trifluoromethyl)pyrrolidin-1-yl}-2,3-dihydro-1H-inden-1-yl)propanamide 
• 1221771-61-4 N-(5-{3-[3,5-bis(trifluoromethyl)phenyl]-3-(trifluoromethyl)pyrrolidin-1-yl}-2,3-dihydro-1H-inden-1-yl)propanamide 
• 1338926-70-7 N-{5-[4,4,4-trifluoro-3-(nitromethyl)-3-(3,4,5-trichloro-phenyl)butanoyl]-2,3-dihydro-1H-inden-1-yl}propanamide 
• 1338926-78-5 5-(3-bromo-4-fluorophenyl)-3-(3,4,5-trichloro-phenyl)-3-(trifluoromethyl)-3,4-dihydro-2H-pyrrole 

Relevant articles and documents

Deconstructive Oxygenation of Unstrained Cycloalkanamines

A deconstructive oxygenation of unstrained primary cycloalkanamines has been developed for the first time using an auto-oxidative aromatization promoted C(sp3)?C(sp3) bond cleavage strategy. This metal-free method involves the substitution reaction of cycloalkanamines with hydrazonyl chlorides and subsequent auto-oxidative annulation to in situ generate pre-aromatics, followed by N-radical-promoted ring-opening and further oxygenation by 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and m-cholorperoxybenzoic acid (mCPBA). Consequently, a series of 1,2,4-triazole-containing acyclic carbonyl compounds were efficiently produced. This protocol features a one-pot operation, mild reaction conditions, high regioselectivity and ring-opening efficiency, broad substrate scope, and is compatible with alkaloids, osamines, and peptides, as well as steroids.

ISOQUINOLINE COMPOUNDS, A PROCESS FOR THEIR PREPARATION, AND PHARMACEUTICAL COMPOSITIONS CONTAINING THEM

A compound of formula (I): wherein the substituents are as defined in the description. Medicinal products containing the same which are useful in treating or preventing pathologies which are the result of activation of the RhoA/ROCK pathway and phosphorylation of the myosin light chain.

METHODS OF PEST CONTROL IN SOYBEAN

The invention provides methods comprising applying to a crop of soybean plants, the locus thereof, or propagation material thereof, a compound of formula (I) wherein -B1-B2-B3- is -C=N-O-, -C=N-CH2- or -N-CH2-CH2-; Y1, Y2 and Y3 are independently CH or nitrogen; wherein no more than two of Y1, Y2 and Y3 are nitrogen and wherein Y2 and Y3 are not both nitrogen; R9 is C1-C4alkyl, C1-C4haloalkyl, C1-C4alkyl-O-CH2-, C1-C4haloalkyl-O-CH2-,C3-C6cycloalkyl, C3-C6cycloalkyl-CH2-, C1-C4alkyl-S-CH2-, C1-C4alkyl-S(O)-CH2-, or C1-C4alkyl-S(O2)-CH2-; X2 is C-X6 or nitrogen; X1, X3 and X6 are independently hydrogen, halogen or trihalomethyl, wherein at least two of X1, X3 and X6 are not hydrogen; X4 is trifluoromethyl, difluoromethyl or chlorodifluoromethyl. Preferably the methods are for control of stinkbugs, in particular from the genus Euschistus and in particular the species Euschistus heros.