18513-05-8Relevant academic research and scientific papers
REACTION OF ARENESULFENYL CHLORIDES WITH N-CHLOROCARBONIMIDIC AND N-CHLOROBENZENECARBOXIMIDIC ESTERS. N-(ETHOXYCARBONYL)- AND N-BENZOYLARENESULFINIMIDOYL CHLORIDES
Levchenko, E. S.,Dubinina, T. N.,Budnik, L. V.,Romanenko, E. A.
, p. 1166 - 1171 (2007/10/02)
In the reaction of arenesulfonyl chlorides with diethyl N-chlorocarbonimidate or N-chlorobenzenecarboximidic esters at 20 deg C 1:1 adducts are formed, and they probably have the structure of tetracoordinated compounds of sulfur.The latter are also formed during the chlorination of N-(arylthio)carbonimidic or N-(arylthio)benzenecarboximidic esters.The obtained compounds are dechlorinated by the action of bases with the formation of N-(arylthio)carbonimidic or N-(arylthio)benzenecarboximidic esters.During acidolysis they split into arenesulfenyl chlorides and the salts of the corresponding carbonimidic and benzenecarboximidic esters.During thermolysis they eliminate alkyl chlorides and are converted into N-(ethoxycarbonyl)- or N-benzoylarenesulfinimidoyl chlorides.
