185321-86-2Relevant academic research and scientific papers
Camphor-based β-hydroxyphosphoryl ligands and their complexes of the type [MoO(O2)2L(H2O)]
Cross, Ronald J.,Farrugia, Louis J.,Newman, Paul D.,Peacock, Robert D.,Stirling, Diane
, p. 4149 - 4150 (2007/10/03)
Homochiral hydroxyphosphoryl compounds, L, such as the novel camphor-based (1R)-endo,endo-3S-(diphenylphosphoryl)-2R-hydroxybornane, have been found to be prevented from behaving as bidentate ligands in the epoxidation catalysts [MoO(O2)2L(H2O)] by unexpectedly strong multiple-bond delocalisation producing near linear Mo-O-P angles.
