18537-19-4Relevant academic research and scientific papers
Nickel(0) catalyzed oxidation of organosilanes to disiloxanes by air as an oxidant
Lv, Haiping,Laishram, Ronibala Devi,Li, Jiayan,Shi, Guangrui,Sun, Weiqing,Xu, Jianbin,Yang, Yong,Luo, Yang,Fan, Baomin
supporting information, p. 971 - 974 (2019/03/07)
We report here an efficient non-aqueous route to symmetrical disiloxanes from their corresponding organosilanes using Ni(COD)2 with 3,4,7,8-tetramethyl-1,10-phenanthroline in air. Our methodology is very simple and high yielding. The reaction mechanism is also proposed.
