185437-39-2Relevant academic research and scientific papers
LXXXIX- Oxidative addition of electrophilic derivatives of αamino acids to platinum(ii) and cobalt(i) complexes: α-transition-metallated amino acids of biologically important ligands
Kayser, Bernd,Noeth, Heinrich,Schmidt, Martin,Steglich, Wolfgang,Beck, Wolfgang
, p. 1617 - 1620 (2007/10/03)
The addition of methyl α-bromohippurate to PtMe2(bipy) gives the α-metallated amlno add derivative (bipy)Me2{Br)PtC(H)(NHCOPh)(CO2Me) as a mixture of isomere la, b of which the Irans adduct la was characterized by X-ray diffraction. Methyl α-bromohippurate and JV-Boc-O-to-sylserine methyl ester are added to [Co(py)(DH)]- (DH= dimethylglyoxime, diphenylglyoxime) to give cobalt(III) complexes 2-5 with a cobalt-carbon bond. VCH Verlagsgesellschar; mbll 1996.
