18547-30-3Relevant articles and documents
Microwave-assisted synthesis of 1,3-bis(3-hydroxypropyl)-1,1,3,3-tetramethyldisiloxane
Cheng, Xitao,Li, Wenhong,Zhang, Cunshe,Huang, Fangfang,Wang, Qianjin,Zhou, Kui
, p. 567 - 571 (2016/01/20)
1,3-Bis(3-hydroxypropyl)-1,1,3,3-tetramethyldisiloxane was synthesized under microwave irradiation. The structure of the compound was analyzed by infrared spectroscopy, nuclear magnetic resonance hydrogen spectroscopy and gas chromatography. The optimal reaction condition was obtained by the single factor method. Under the optimal condition, the overall yield could reach 83.9 % and the purity of 1,3-bis(3-hydroxypropyl)-1,1,3,3-tetramethyldisiloxane was 99.1 %. It is found that under microwave radiation the reactions are very rapid with good yield, better quality and less time is required for the completion of the reaction.
Synthesis of disiloxanes containing hydroxyalkyl groups
Braun, F.,Willner, L.,Hess, M.,Kosfeld, R.
, p. 63 - 68 (2007/10/02)
Four 1,3-bis(ω-hydroxyalkyl)tetramethyldisiloxanes 2O (I; n = 3-6) were synthsized by methanolysis of the correspondig trimethylsilylterminated disiloxanes (III).The latter were obtained from 1,1,3,3-tetramethyldisiloxane (II) and the appropriate (ω-alkenyloxy)trimethylsilanes (IV).Under acidic conditions III formed in addition to I, the corresponding (ω-hydroxyalkyl)pentamethyldisiloxanes HO(CH2)nSiMe2OSiMe3 (V; n = 3-6).