18547-30-3Relevant academic research and scientific papers
Microwave-assisted synthesis of 1,3-bis(3-hydroxypropyl)-1,1,3,3-tetramethyldisiloxane
Cheng, Xitao,Li, Wenhong,Zhang, Cunshe,Huang, Fangfang,Wang, Qianjin,Zhou, Kui
, p. 567 - 571 (2016/01/20)
1,3-Bis(3-hydroxypropyl)-1,1,3,3-tetramethyldisiloxane was synthesized under microwave irradiation. The structure of the compound was analyzed by infrared spectroscopy, nuclear magnetic resonance hydrogen spectroscopy and gas chromatography. The optimal reaction condition was obtained by the single factor method. Under the optimal condition, the overall yield could reach 83.9 % and the purity of 1,3-bis(3-hydroxypropyl)-1,1,3,3-tetramethyldisiloxane was 99.1 %. It is found that under microwave radiation the reactions are very rapid with good yield, better quality and less time is required for the completion of the reaction.
Synthesis and characterization of some bis(hydroxyalkyl)- and bis(hydroxyester)-functionalized disiloxanes
Pusztai, Erika,Nagy, Jozsef,Wagner, Oedoen
, p. 91 - 97 (2013/03/13)
Novel hydroxyester disiloxanes (1,3-bis(6-hydroxyhexa noylmethyl)-1,1,3,3- tetramethyl disiloxane and 3-bis(2-hydroxypropanoylmethyl)tetramethyl disiloxane) were synthesized, and preparation of other known monomers, namely 1,3-bis(hydroxypropyl)-1,1,3,3-tetramethyl disiloxane, 1,3- bis(hydroxyethoxypropyl)-1,1,3,3-tetramethyl disiloxane and 1,3- bis(hydroxymethyl)-1,1,3,3-tetramethyl disiloxane was developed to obtain better yields and reduce production time and expense. All compounds were characterized by infrared spectroscopy, using 1H NMR, 13C NMR, and 29Si NMR and were reacted with diisocyanates, resulting in poly(siloxane-urethane) copolymers with unique properties.
Synthesis of disiloxanes containing hydroxyalkyl groups
Braun, F.,Willner, L.,Hess, M.,Kosfeld, R.
, p. 63 - 68 (2007/10/02)
Four 1,3-bis(ω-hydroxyalkyl)tetramethyldisiloxanes 2O (I; n = 3-6) were synthsized by methanolysis of the correspondig trimethylsilylterminated disiloxanes (III).The latter were obtained from 1,1,3,3-tetramethyldisiloxane (II) and the appropriate (ω-alkenyloxy)trimethylsilanes (IV).Under acidic conditions III formed in addition to I, the corresponding (ω-hydroxyalkyl)pentamethyldisiloxanes HO(CH2)nSiMe2OSiMe3 (V; n = 3-6).
