185758-04-7Relevant academic research and scientific papers
Supramolecular self-organization in methyl(diphenylphosphinothioato)mercury(II), [HgMe{S(O)PPh2}], a polymer containing Hg2O2P2S2 eight-membered rings interconnected through secondary Hg?O bonds
Casas, José S.,Casti?eiras, Alfonso,Haiduc, Ionel,Sánchez, Agustín,Sordo, José,Vázquez-López, Ezequiel M.
, p. 781 - 787 (1997)
Methyl- and phenylmercury(II) diphenylphosphinothioates [HgR[S(O)PPh2}] (R = Me and Ph) were synthesized. In [HgMe{S(O)PPh2}] the mercury atom is coordinated to the methyl carbon atom and to the ligand sulfur atom. Intermolecular Hg?O interactions form a supramolecular ribbon structure along the b-axis. The IR and NMR (1H, 13C, 31P and 199Hg) spectra of the two compounds are discussed. Copyright
