185805-26-9Relevant academic research and scientific papers
Use of Silicon-Based Tethers to Control Diastereofacial Selectivity in Azomethine Ylide Cycloadditions
Garner, Philip,Cox, Philip B.,Anderson, James T.,Protasiewicz, John,Zaniewski, Rebecca
, p. 493 - 498 (2007/10/03)
A novel approach to controlling the diastereofacial selectivity of intramolecular dipolar cycloadditions of azomethine ylides (cf. 9 → 8) by varying the structure a silicon-based tether is described. A correlation is found between the length of the tether
Tether-Mediated Stereocontrol in Intramoleclar Azomethine Ylide Cycloadditions
Garner, Philip P.,Cox, Philip B.,Klippenstein, Stephen J.,Youngs, Wiley J.,McConville, David B.
, p. 6510 - 6511 (2007/10/02)
The computationally guided design of a silicon-based tether system for stereoselective intramolecular azomethine ylide cycloadditions is described.
