791810-66-7Relevant academic research and scientific papers
Tether-Mediated Stereocontrol in Intramoleclar Azomethine Ylide Cycloadditions
Garner, Philip P.,Cox, Philip B.,Klippenstein, Stephen J.,Youngs, Wiley J.,McConville, David B.
, p. 6510 - 6511 (1994)
The computationally guided design of a silicon-based tether system for stereoselective intramolecular azomethine ylide cycloadditions is described.
Stereoselective total synthesis of (+)-streptazolin by using a temporary silicon-tethered RCM strategy
Li, Fangzheng,Miller, Marvin J.
, p. 5221 - 5227 (2007/10/03)
A stereoselective total synthesis of (+)-streptazolin 1 was accomplished starting from readily available aminocyclopentenol (-)-7. The synthetic sequence highlights an intramolecular aldol condensation strategy to construct the piperidine core and a silic
Synthetic studies on bradykinin antagonist martinellines: Construction of a pyrrolo[3,2-c]quinoline skeleton using silicon-tether RCM reaction and allylic amination
Hara, Osamu,Sugimoto, Kazuhiko,Hamada, Yasumasa
, p. 9381 - 9390 (2007/10/03)
The pyrrolo[3,2-c]quinoline consisting of a core structure of martinellines, the first naturally occurring heterocycle, was prepared through silicon-tether ring-closing metathesis reaction and intramolecular allylic amination as key steps. Graphical Abstr
