136365-87-2Relevant academic research and scientific papers
Chemistry of silyl thioketones. Part 10. Synthesis and reactivity of α-silyl vinyl sulfldes
Bonini, Bianca Flavia,Comes-Franchini, Mauro,Fochi, Mariafrancesca,Mazzanti, Germana,Peri, Francesca,Ricci, Alfredo
, p. 2803 - 2809 (2007/10/03)
Aliphatic silyl thioketones containing an α-hydrogen atom undergo enethiolization to Z-α-silyl enethiols 2. Compounds 2 react with a variety of halides R3X to give open-chain α-silyl vinyl sulfides 3. Protiodesilylation of 3 was achieved upon treatment with fluoride ion to give vinyl sulfides 4. Reaction of 3 with Grignard reagents, in the presence of an appropriate nickel catalyst, results in a series of vinylsilanes 5 with a specific geometry.
STUDIES ON THE SYNTHETIC USE OF STEREODEFINED OLEFINS WITH GEMINAL TRIMETHYLSILYL AND TRIMETHYLSTANNYL SUBSTITUENTS
Rossi, Renzo,Carpita, Adriano,Bellina, Fabio,Santis Massimo De
, p. 261 - 271 (2007/10/02)
The synthetic use of 2-alkyl and 2-(hetero)aryl substituted (Z)- and (E)-1-trimethylsilyl-1-trimethylstannylethenes of general formula (Z)-2, (E)-2, (Z)-3 and (E)-3, via the corresponding 1-silylethenyllithiums prepared by tin-lithium exchange reactions a
