185847-85-2Relevant academic research and scientific papers
Direct C-H Allylation of N-Acyl/Sulfonyl Tetrahydroisoquinolines and Analogues
Yan, Changcun,Liu, Yuxiu,Wang, Qingmin
supporting information, p. 5714 - 5717 (2015/12/01)
A highly efficient direct C-H allylation reaction at the α position of N-acyl/sulfonyl tetrahydroisoquinolines under mild conditions was developed. The reaction was also suitable for allylation of other protected nitrogen-containing heterocycles. Several
Complexation promoted additions to N-benzoyliminopyridinium ylides. A novel and highly regioselective approach to polysubstituted piperidines
Legault, Claude,Charette, Andre B.
, p. 6360 - 6361 (2007/10/03)
Unprecedented regioselectivities were observed for the addition of different organometallic nucleophiles to N-benzoyliminopyridinium ylides. Even benzylic and branched aliphatic Grignard reagents, which usually give substantial amounts of 1,4-adducts, sho
Exploitation of palladium-catalyzed reductive enyne cyclization in the synthesis of (-)-4a,5-dihydrostreptazolin
Yamada, Hironari,Aoyagi, Sakae,Kibayashi, Chihiro
, p. 8787 - 8790 (2007/10/03)
Hydroxyl-promoted reductive cyclization of enyne compounds catalyzed by Pd(OAc)2-BBEDA was explored and found to effect constructing the pyrindine framework with the alkylidene appendage. This methodology was applied to the stereoselective synthesis of (-)-4a,5-dihydrostreptazolin.
