185851-76-7

Upstream product

• 68760-11-2 1-(4-nitrophenyl)-3-N,N-dimethylamino-2-propen-1-one 
• 124-40-3 dimethyl amine 
• 100-19-6 (4-nitrophenyl)ethanone 

Downstream Products

• 198757-67-4 2-[(Z)-Ethylimino]-N,N-dimethyl-2-(4-nitro-phenyl)-thioacetamide 
• 198757-46-9 N,N-Dimethyl-2-(4-nitro-phenyl)-2-[(E)-phenylimino]-thioacetamide 
• 185851-71-2 N,N-dimethyl-2-(4-nitrophenyl)-2-thioethane-thioamide 

Relevant academic research and scientific papers

Synthesis of α-Keto Thioamides by Metal-Free C-C Bond Cleavage in Enaminones Using Elemental Sulfur

An unprecedented method for cleaving the C-C bond in N,N-disubstituted enaminones in the presence of elemental sulfur and N,N-dimethyl-4-aminopyridine is disclosed. Without using any metal catalyst or additive, the cascade functionalization of both C?C an

Summary - α-Thioxothioamides : [4 + 2] cycloaddition reactions with dimethyl acetylenedicarboxylate and methyl propiolate

The title compounds are prepared from methyl ketones through a three-step reaction: chloration with thionyl chloride; amination of the resulting α-chloro-β-oxosulfenyl chlorides; and thionation of α-oxothioamides with Lawesson's reagent. Two competitive h