185950-43-0Relevant academic research and scientific papers
Neutral thiolates and a iodothiolate of antimony(III). Crystal structures of Sb(SC6H5)3, Sb(SC6H2Me3-2,4,6)3, and SbI(SC6H2Me3-2,4,6)2
Peters,Saak,Pohl
, p. 2119 - 2123 (1996)
The crystal structures of Sb(SC6H5)3 (1), Sb(SC6 · H2Me3-2,4,6)3 (2), and the novel compound SbI(SC6H2Me3-2,4,6)2 (3) have been determined by X-ray crystallography. In addition to the expected trigonal pyramidal coordination of antimony intermolecular interactions are observed for 1 (Sb ... C: 363.3 pm) and 3 (Sb ... S: 2x369.4pm) but not for 2. The reasons for these differences are discussed. Johann Ambrosius Barth 1996.
