Zeitschrift fur Anorganische und Allgemeine Chemie p. 2119 - 2123 (1996)
Update date:2022-08-03
Topics:
Peters
Saak
Pohl
The crystal structures of Sb(SC6H5)3 (1), Sb(SC6 · H2Me3-2,4,6)3 (2), and the novel compound SbI(SC6H2Me3-2,4,6)2 (3) have been determined by X-ray crystallography. In addition to the expected trigonal pyramidal coordination of antimony intermolecular interactions are observed for 1 (Sb ... C: 363.3 pm) and 3 (Sb ... S: 2x369.4pm) but not for 2. The reasons for these differences are discussed. Johann Ambrosius Barth 1996.
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(1968)Doi:10.1016/j.chempr.2020.07.023
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