185987-56-8

Upstream product

• 201603-52-3 tert-Butyl-dimethyl-((2R,3S,4R)-2,3,4-tris-benzyloxy-5,5-bis-ethylsulfanyl-pentyloxy)-silane 
• 100-39-0 benzyl bromide 
• 612-05-5 methyl-β-D-xylopyranoside 
• 201603-40-9 (2R,3S,4R)-5-(tert-Butyl-dimethyl-silanyloxy)-1,1-bis-ethylsulfanyl-pentane-2,3,4-triol 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 13263-74-6 D-xylose diethyl dithioacetal 

Downstream Products

• 185987-64-8 C₆₀H₈₄N₂O₁₅S 
• 185987-63-7 C₅₅H₈₂N₂O₁₃ 
• 185987-62-6 C₅₄H₈₀N₂O₁₃ 
• 157761-57-4 (1R,2R,3S,4R,6R)-2,3,4-Tris-benzyloxy-5-methylene-7-oxa-bicyclo[4.1.0]heptane 
• 215303-21-2 (2S,3S,4S,5S,6R)-4,5,6-Tris-benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-2,3-dihydroxy-heptanoic acid methyl ester 
• 215303-26-7 (2R,3R)-3-((E)-(1R,2S,3R)-1,2,3-Tris-benzyloxy-5-methoxycarbonyl-pent-4-enyl)-oxirane-2-carboxylic acid methyl ester 
• 215303-18-7 (2R,3R)-3-((E)-(1R,2S,3R)-1,2,3-Tris-benzyloxy-5-methoxycarbonyl-pent-4-enyl)-oxirane-2-carboxylic acid 
• 215303-23-4 (2R,3R)-3-[(1R,2S,3R)-1,2,3-Tris-benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-butyl]-oxirane-2-carboxylic acid methyl ester 
• 215303-30-3 ((1S,2R,3R,4S,5R,6S)-3,4,5-Tris-benzyloxy-7-oxa-bicyclo[4.1.0]hept-2-yl)-acetic acid methyl ester 
• 215303-24-5 (2R,3R)-3-((1R,2S,3R)-1,2,3-Tris-benzyloxy-4-hydroxy-butyl)-oxirane-2-carboxylic acid methyl ester 
• 215303-38-1 ((1R,2R,3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-7-oxa-bicyclo[4.1.0]hept-2-yl)-acetic acid 
• 195873-64-4 3,4,5-tri-O-benzyl-1,2-dideoxy-D-xylohept-1-enitol 
• 201603-56-7 ((1R,2R,3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-7-oxa-bicyclo[4.1.0]hept-2-yl)-acetic acid methyl ester 
• 201603-48-7 (3S,4R,5R,6S)-4,5,6-Tris-benzyloxy-3-vinyl-oct-7-enoic acid methyl ester 

Relevant academic research and scientific papers

Free Radical Studies and Solutions to the Synthesis of (+)-Cyclophellitol

D-Xylose serves as a starting material for approaches to the synthesis of the glucosidase inhibitors, (+)-cyclophellitol (1) and (+)-epi-cyclophellitol (2). An investigation of the cyclization of diastereomeric oxiranyl radicals to achieve this goal was m

Chimeric azalides with functionalized western portions

A series of chimeric azalides which are homologous to the potent azalide antibiotic 9-deoxo-8a-aza-8a-homoerythromycin A (2) in their eastern halves, but which have functionally complex western halves derived from a variety of sources, including carbohydr

Process of producing 8A- and 9A-azalide antibiotics

A process of producing 8a- and 9a- azalide compounds is disclosed, comprised of reacting an 8a- aza or 9a- aza azalide eastern fragment or a derivative thereof with a compound of the formula: wherein X and Y are appropriate reactive groups and A' is a fragment or compound which forms the western portion of the azalide, and cyclizing this intermediate to form the target 8a- or 9a-azalide compound. Compounds of formula I, II and III as well as other azalides can be synthesized according to this process.